Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach

This is the peer reviewed version of the following article: Guisán-Ceinos, M., Parra, A., Martín-Heras, V. and Tortosa, M. (2016), Enantioselective Synthesis of Cyclobutylboronates via a Copper-Catalyzed Desymmetrization Approach. Angew. Chem., which has been published in final form at http://dx.doi...

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Detalles Bibliográficos
Autores: Guisán-Ceinos, M., Parra Alfambra, Ana María, Martín-Heras, Víctor, Tortosa Manzanares, Mariola
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/671466
Acceso en línea:http://hdl.handle.net/10486/671466
https://dx.doi.org/10.1002/ange.201601976
Access Level:acceso abierto
Palabra clave:Asymmetric catalysis
Cyclobutanes
Boron
Copper
Química
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spelling Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approachGuisán-Ceinos, M.Parra Alfambra, Ana MaríaMartín-Heras, VíctorTortosa Manzanares, MariolaAsymmetric catalysisCyclobutanesBoronCopperQuímicaThis is the peer reviewed version of the following article: Guisán-Ceinos, M., Parra, A., Martín-Heras, V. and Tortosa, M. (2016), Enantioselective Synthesis of Cyclobutylboronates via a Copper-Catalyzed Desymmetrization Approach. Angew. Chem., which has been published in final form at http://dx.doi.org/10.1002/ange.201601976. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.In this report, the first catalytic enantioselective synthesis of cyclobutylboronates, using a chiral copper(I) complex, is disclosed. A broad variety of cyclobutanes have been prepared with consistently high levels of diastereo- and enantiocontrol. Moreover, this method constitutes the first report of an enantioselective desymmetrization of meso-cyclobutenes to prepare chiral cyclobutanesWe thank the European Research Council (ERC-337776) and MINECO (CTQ2012-35957) for financial support. M. T. and A. P. thank MICINN for RyC and JdC contractsWiley - V C H Verlag GmbH & Co. KGaADepartamento de Química OrgánicaFacultad de Ciencias20162016-05-09research articlehttp://purl.org/coar/resource_type/c_2df8fbb1AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/671466https://dx.doi.org/10.1002/ange.201601976reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengEuropean Commission http://dx.doi.org/10.13039/501100000780 Framework Programme Seven 337776open accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/6714662026-06-23T12:46:27Z
dc.title.none.fl_str_mv Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach
title Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach
spellingShingle Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach
Guisán-Ceinos, M.
Asymmetric catalysis
Cyclobutanes
Boron
Copper
Química
title_short Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach
title_full Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach
title_fullStr Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach
title_full_unstemmed Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach
title_sort Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach
dc.creator.none.fl_str_mv Guisán-Ceinos, M.
Parra Alfambra, Ana María
Martín-Heras, Víctor
Tortosa Manzanares, Mariola
author Guisán-Ceinos, M.
author_facet Guisán-Ceinos, M.
Parra Alfambra, Ana María
Martín-Heras, Víctor
Tortosa Manzanares, Mariola
author_role author
author2 Parra Alfambra, Ana María
Martín-Heras, Víctor
Tortosa Manzanares, Mariola
author2_role author
author
author
dc.contributor.none.fl_str_mv Departamento de Química Orgánica
Facultad de Ciencias
dc.subject.none.fl_str_mv Asymmetric catalysis
Cyclobutanes
Boron
Copper
Química
topic Asymmetric catalysis
Cyclobutanes
Boron
Copper
Química
description This is the peer reviewed version of the following article: Guisán-Ceinos, M., Parra, A., Martín-Heras, V. and Tortosa, M. (2016), Enantioselective Synthesis of Cyclobutylboronates via a Copper-Catalyzed Desymmetrization Approach. Angew. Chem., which has been published in final form at http://dx.doi.org/10.1002/ange.201601976. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
publishDate 2016
dc.date.none.fl_str_mv 2016
2016-05-09
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/671466
https://dx.doi.org/10.1002/ange.201601976
url http://hdl.handle.net/10486/671466
https://dx.doi.org/10.1002/ange.201601976
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission http://dx.doi.org/10.13039/501100000780 Framework Programme Seven 337776
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley - V C H Verlag GmbH & Co. KGaA
publisher.none.fl_str_mv Wiley - V C H Verlag GmbH & Co. KGaA
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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