Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production

Línea Investigación: Línea 5. Producción de hidrógeno

Detalles Bibliográficos
Autores: Marugán, J., Botas, J.A., Molina, R., Herradón, C.
Tipo de recurso: artículo
Fecha de publicación:2012
País:España
Institución:Universidad Rey Juan Carlos
Repositorio:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
OAI Identifier:oai:burjcdigital.urjc.es:10115/11516
Acceso en línea:http://hdl.handle.net/10115/11516
Access Level:acceso abierto
Palabra clave:Energías Renovables
Thermochemical Water Splitting
Hydrogen Production
Manganese Oxide
Kinetic Modeling
2210.31 Termoquímica
id ES_1291f064366f1f261d844cd73e04da15
oai_identifier_str oai:burjcdigital.urjc.es:10115/11516
network_acronym_str ES
network_name_str España
repository_id_str
spelling Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen productionMarugán, J.Botas, J.A.Molina, R.Herradón, C.Energías RenovablesThermochemical Water SplittingHydrogen ProductionManganese OxideKinetic Modeling2210.31 TermoquímicaLínea Investigación: Línea 5. Producción de hidrógenoThis work reports the kinetic study of the first step of the Mn2O3/MnO thermochemical cycle for hydrogen production by water splitting. The reaction kinetics of Mn (III) oxide thermal reduction has been evaluated using dynamic thermogravimetric analysis at constant heating rate under nitrogen flow. This way the reaction rate can be described as a function of temperature and different kinetic models were fitted to the experimental data obtained from thermogravimetric experiments. A good fitting can be observed for each experiment, although a significant disparity in the values estimated for the Arrhenius parameters has been found (activation energies and pre-exponential factors). Unique values for the kinetic parameters have been calculated by application of a multivariate non-linear regression method for the simultaneous fitting of data from all the experiments carried out at different heating ramps. However, also in this case the values of the Arrhenius parameters are significantly different depending on the chosen kinetic equation. Optimal kinetic parameters have been finally calculated through the estimation of activation energy values by model-free isoconversional methods and using a rigorous multivariate nonlinear regression for the calculation of the model-dependant pre-exponential factors.Tecnología Química y EnergéticaElsevier201320132012info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10115/11516reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlosinstname:Universidad Rey Juan CarlosInglésAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:burjcdigital.urjc.es:10115/115162026-06-24T12:48:17Z
dc.title.none.fl_str_mv Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production
title Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production
spellingShingle Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production
Marugán, J.
Energías Renovables
Thermochemical Water Splitting
Hydrogen Production
Manganese Oxide
Kinetic Modeling
2210.31 Termoquímica
title_short Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production
title_full Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production
title_fullStr Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production
title_full_unstemmed Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production
title_sort Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production
dc.creator.none.fl_str_mv Marugán, J.
Botas, J.A.
Molina, R.
Herradón, C.
author Marugán, J.
author_facet Marugán, J.
Botas, J.A.
Molina, R.
Herradón, C.
author_role author
author2 Botas, J.A.
Molina, R.
Herradón, C.
author2_role author
author
author
dc.subject.none.fl_str_mv Energías Renovables
Thermochemical Water Splitting
Hydrogen Production
Manganese Oxide
Kinetic Modeling
2210.31 Termoquímica
topic Energías Renovables
Thermochemical Water Splitting
Hydrogen Production
Manganese Oxide
Kinetic Modeling
2210.31 Termoquímica
description Línea Investigación: Línea 5. Producción de hidrógeno
publishDate 2012
dc.date.none.fl_str_mv 2012
2013
2013
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10115/11516
url http://hdl.handle.net/10115/11516
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
instname:Universidad Rey Juan Carlos
instname_str Universidad Rey Juan Carlos
reponame_str BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
collection BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869403626074537984
score 15,81155

Similares en LA Referencia