Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal properties

This article belongs to the Special Issue Thermal Transport in Nanostructures and Nanomaterials.

Detalhes bibliográficos
Autores: Rodríguez-Laguna, María del Rocío, Gómez-Romero, P., Sotomayor Torres, C. M., Chávez-Angel, Emigdio
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/182949
Acesso em linha:http://hdl.handle.net/10261/182949
Access Level:acceso abierto
Palavra-chave:Raman of nanofluids
Enhancement of thermal conductivity
Nanofluids
Graphene
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spelling Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal propertiesRodríguez-Laguna, María del RocíoGómez-Romero, P.Sotomayor Torres, C. M.Chávez-Angel, EmigdioRaman of nanofluidsEnhancement of thermal conductivityNanofluidsGrapheneThis article belongs to the Special Issue Thermal Transport in Nanostructures and Nanomaterials.It is well known that by dispersing nanoparticles in a fluid, the thermal conductivity of the resulting nanofluid tends to increase with the concentration of nanoparticles. However, it is not clear what the mechanism behind this phenomenon is. Raman spectroscopy is a characterization technique connecting the molecular and macroscopic world, and therefore, it can unravel the puzzling effect exerted by the nanomaterial on the fluid. In this work, we report on a comparative study on the thermal conductivity, vibrational spectra and viscosity of graphene nanofluids based on three different amides: N, N-dimethylacetamide (DMAc); N, N-dimethylformamide (DMF); and N-methyl-2-pyrrolidinone (NMP). A set of concentrations of highly stable surfactant-free graphene nanofluids developed in-house was prepared and characterized. A correlation between the modification of the vibrational spectra of the fluids and an increase in their thermal conductivity in the presence of graphene was confirmed. Furthermore, an explanation of the non-modification of the thermal conductivity in graphene-NMP nanofluids is given based on its structure and a peculiar arrangement of the fluid.ICN2 acknowledges support from Severo Ochoa Program (MINECO, Grant SEV-2017-0706) and funding from the CERCA Programme/ Generalitat de Catalunya. Funding from the Spanish Ministry (MINECO/FEDER: MAT2015-68394-R NaCarFLOW and FIS2015-70862-P PHENTOM) is also acknowledged.Peer reviewedMultidisciplinary Digital Publishing InstituteMinisterio de Economía y Competitividad (España)Agencia Estatal de Investigación (España)Generalitat de CatalunyaEuropean CommissionConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2019201920192019info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/182949reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/SEV-2017-0706SEV-2017-0706/AEI/10.13039/501100011033info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2015-68394-Rinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/FIS2015-70862-Phttps://doi.org/10.3390/nano9050804Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1829492026-05-22T06:33:51Z
dc.title.none.fl_str_mv Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal properties
title Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal properties
spellingShingle Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal properties
Rodríguez-Laguna, María del Rocío
Raman of nanofluids
Enhancement of thermal conductivity
Nanofluids
Graphene
title_short Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal properties
title_full Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal properties
title_fullStr Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal properties
title_full_unstemmed Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal properties
title_sort Modification of the raman spectra in graphene-based nanofluids and its correlation with thermal properties
dc.creator.none.fl_str_mv Rodríguez-Laguna, María del Rocío
Gómez-Romero, P.
Sotomayor Torres, C. M.
Chávez-Angel, Emigdio
author Rodríguez-Laguna, María del Rocío
author_facet Rodríguez-Laguna, María del Rocío
Gómez-Romero, P.
Sotomayor Torres, C. M.
Chávez-Angel, Emigdio
author_role author
author2 Gómez-Romero, P.
Sotomayor Torres, C. M.
Chávez-Angel, Emigdio
author2_role author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (España)
Agencia Estatal de Investigación (España)
Generalitat de Catalunya
European Commission
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Raman of nanofluids
Enhancement of thermal conductivity
Nanofluids
Graphene
topic Raman of nanofluids
Enhancement of thermal conductivity
Nanofluids
Graphene
description This article belongs to the Special Issue Thermal Transport in Nanostructures and Nanomaterials.
publishDate 2019
dc.date.none.fl_str_mv 2019
2019
2019
2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/182949
url http://hdl.handle.net/10261/182949
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/SEV-2017-0706
SEV-2017-0706/AEI/10.13039/501100011033
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2015-68394-R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/FIS2015-70862-P
https://doi.org/10.3390/nano9050804

dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
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