Gas spreading and mixing in heterogeneous porous media for underground hydrogen storage

The efficiency of operations of underground hydrogen storage (UHS) depends largely on the spreading and mixing behavior of the fluids, affecting gas displacement during injection, and purity upon extraction. Despite this, the link between gas spreading and mixing and the degree of heterogeneity in t...

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Detalles Bibliográficos
Autores: Visentini, Alejandro F., Hidalgo, Juan J., Cueto-Felgueroso, Luis, Dentz, Marco
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/392889
Acceso en línea:http://hdl.handle.net/10261/392889
https://api.elsevier.com/content/abstract/scopus_id/105007918995
Access Level:acceso abierto
Palabra clave:Viscous fingering
Fluid mixing
Fluid spreading
Gas compressibility
Gravity override
Hydrogen injection efficiency
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Descripción
Sumario:The efficiency of operations of underground hydrogen storage (UHS) depends largely on the spreading and mixing behavior of the fluids, affecting gas displacement during injection, and purity upon extraction. Despite this, the link between gas spreading and mixing and the degree of heterogeneity in the reservoir's permeability remains largely unexplored, even more when accounting for the highly non-linear gas flow dynamics that lead to gas compression, gravity override and viscous fingering. We conduct highly-resolved numerical simulations of isothermal hydrogen injection into a methane-saturated heterogeneous reservoir featuring a log-normal distribution of permeability. We examine the evolution of standard measures of spreading and mixing, namely, the interface length, the longitudinal spread and the volume of mixing, as a function of the variance of the log-permeability, σ<inf>Y</inf><sup>2</sup>, which quantifies the degree of heterogeneity, and the Péclet number, Pe, which characterizes the transport regime. The examined measures increase over time at faster rates as σ<inf>Y</inf><sup>2</sup> increases, indicating enhanced spreading and mixing by permeability-induced flow heterogeneity. Gravity override and gas compressibility lead to temporal scalings departing from diffusive, ballistic and dispersive scalings expected for incompressible flows with constant density and viscosity. Gravity override, linked with super-ballistic scalings, diminishes with σ<inf>Y</inf><sup>2</sup>, due to the decreased density contrasts by mixing, and the decreased vertical flow rate by low permeability zones. Gas compression, increasing with Pe due to the higher injection rate, is linked with non-monotonic growth rates of the spread and mixing volume. Viscous fingering effects appear to be of second order due to the moderate viscosity contrast between hydrogen and methane (∼0.3). We use the segregation intensity as a measure of hydrogen injection efficiency, ϵ, defined as the degree of hydrogen segregation, relative to the amount of injected gas. The maximum values attained by ϵ become smaller as σ<inf>Y</inf><sup>2</sup> increases, and occur at earlier times, confirming that hydrogen injection is less efficient as the heterogeneity in the reservoir increases. Further, the non-monotonic evolution of ϵ indicates a fluctuating dominance between injection and mixing rates during the reservoir's saturation.