Fabrication and characterization of large-area suspended MoSe2 crystals down to the monolayer

Many layered materials, such as graphene and transition metal dichalcogenides, can be exfoliated down to atomic or molecular monolayers. These materials exhibit exciting material properties that can be exploited for several promising device concepts. Thinner materials lead to an increased surface-to...

Descripción completa

Detalles Bibliográficos
Autores: Varghese, Sebin|||0000-0001-7204-7121, Saleta Reig, David|||0000-0003-3189-2331, Mehew, Jake Dudley|||0000-0002-8859-9374, Block, Alexander|||0000-0001-9288-5405, Sachat, Alexandros el|||0000-0003-3798-9724, Chávez Ángel, Emigdio|||0000-0002-9783-0806, Sledzinska, Marianna|||0000-0001-8592-1121, Ballesteros, Belén|||0000-0002-1958-8911, Sotomayor Torres, Clivia M.|||0000-0001-9986-2716, Tielrooij, Klaas-Jan|||0000-0002-0055-6231
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:268430
Acceso en línea:https://ddd.uab.cat/record/268430
https://dx.doi.org/urn:doi:10.1088/2515-7639/ac2060
Access Level:acceso abierto
Palabra clave:Suspended flakes
Transition metal dichalcogenides
MoSe2
Dry-transfer
Optical absorption
Descripción
Sumario:Many layered materials, such as graphene and transition metal dichalcogenides, can be exfoliated down to atomic or molecular monolayers. These materials exhibit exciting material properties that can be exploited for several promising device concepts. Thinner materials lead to an increased surface-to-volume ratio, with mono- and bi-layers being basically pure surfaces. Thin crystals containing more than two layers also often behave as an all-surface material, depending on the physical property of interest. As a result, flakes of layered materials are typically highly sensitive to their environment, which is undesirable for a broad range of studies and potential devices. Material systems based on suspended flakes overcome this issue, yet often require complex fabrication procedures. Here, we demonstrate the relatively straightforward fabrication of exfoliated MoSe flakes down to the monolayer, suspended over unprecedentedly large holes with a diameter of 15 µm. We describe our fabrication methods in detail, present characterization measurements of the fabricated structures, and, finally, exploit these suspended flakes for accurate optical absorption measurements.