Nickel phosphonate MOF as efficient water splitting photocatalyst

[EN] A novel microporous two-dimensional (2D) Ni-based phosphonate metal-organic framework (MOF; denoted as IEF-13) has been successfully synthesized by a simple and green hydrothermal method and fully characterized using a combination of experimental and computational techniques. Structure resoluti...

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Detalles Bibliográficos
Autores: Salcedo-Abraira, Pablo, Vilela, Sérgio M. F., Babaryk, Artem A., Salles, Fabrice, Horcajada, Patricia, Cabrero-Antonino, Maria, Navalón Oltra, Sergio|||0000-0001-8423-0759, García Gómez, Hermenegildo|||0000-0002-9664-493X, Ponce Gregorio, Pedro|||0000-0002-9548-767X
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/186160
Acceso en línea:https://riunet.upv.es/handle/10251/186160
Access Level:acceso abierto
Palabra clave:Metal-organic framework
Phosphonates
Photocatalysis
Water splitting
QUIMICA ORGANICA
Descripción
Sumario:[EN] A novel microporous two-dimensional (2D) Ni-based phosphonate metal-organic framework (MOF; denoted as IEF-13) has been successfully synthesized by a simple and green hydrothermal method and fully characterized using a combination of experimental and computational techniques. Structure resolution by single-crystal X-ray diffraction reveals that IEF-13 crystallizes in the triclinic space group P-i having bi-octahedra nickel nodes and a photo/electroactive tritopic phosphonate ligand. Remarkably, this material exhibits coordinatively unsaturated nickel(II) sites, free-PO3H2 and-PO3H acidic groups, a CO2 accessible microporosity, and an exceptional thermal and chemical stability. Further, its in-deep optoelectronic characterization evidences a photoresponse suitable for photocatalysis. In this sense, the photocatalytic activity for challenging H-2 generation and overall water splitting in absence of any co-catalyst using UV-Vis irradiation and simulated sunlight has been evaluated, constituting the first report for a phosphonate-MOF photocatalyst. IEF-13 is able to produce up to 2,200 mu mol of H-2 per gram using methanol as sacrificial agent, exhibiting stability, maintaining its crystal structure and allowing its recycling. Even more, 170 mu mol of H-2 per gram were produced using IEF-13 as photocatalyst in the absence of any co-catalyst for the overall water splitting, being this reaction limited by the O-2 reduction. The present work opens new avenues for further optimization of the photocatalytic activity in this type of multifunctional materials.