A study of overripe seed byproducts from sun-dried grapes by dispersive raman spectroscopy

Overripe seeds from sun-dried grapes submitted to postharvest dehydration constitute a scarcely investigated class of vinification byproduct with limited reports on their phenolic composition and industrial applications. In this study, Raman spectroscopy was applied to characterize a selection of ov...

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Detalles Bibliográficos
Autores: Rivero Granados, Francisco José, Ciaccheri, Leonardo, González-Miret Martín, María Lourdes, Rodríguez Pulido, Francisco José, Mencaglia, Andrea A., Heredia Mira, Francisco José, Mignani, Anna G., Gordillo Arrobas, Belén
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/128913
Acceso en línea:https://hdl.handle.net/11441/128913
https://doi.org/10.3390/foods10030483
Access Level:acceso abierto
Palabra clave:Grape byproducts
Overripe seeds
Phenolics
Postharvest sun drying
Raman scattering
Vibrational spectroscopy
Descripción
Sumario:Overripe seeds from sun-dried grapes submitted to postharvest dehydration constitute a scarcely investigated class of vinification byproduct with limited reports on their phenolic composition and industrial applications. In this study, Raman spectroscopy was applied to characterize a selection of overripe seed byproducts from different white grapes (cv. Moscatel, cv. Pedro Ximénez and cv. Zalema) submitted to postharvest sun drying. The Raman measurements were taken using a 1064 nm excitation laser in order to mitigate the fluorescent effect and the dispersive detection scheme allowed a compactness of the optical system. Spectroscopic data were processed by a prin-cipal component analysis to reduce the dimensionality and partner recognition. The evolution of the Raman spectrum during the overripening process was compared with the phenolic composition of grape seeds, which was determined by rapid resolution liquid chromatography/mass spectrom-etry (RRLC/MS). A multivariate processing of the spectroscopic data allowed the classification of overripe seeds according to the grape variety and the monitoring of stages of the postharvest sun drying process.