Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis

We present an efficient and green methodology for the synthesis of glycerol monoethers, starting from glycidol and different alcohols, by means of heterogeneous acid catalysis. A scope of Brønsted and Lewis acid catalysts were applied to the benchmark reaction of glycidol and methanol. The selected...

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Detalles Bibliográficos
Autores: Pires, Elisabet, García, José Ignacio, Leal-Duaso, Alejandro, Mayoral, José Antonio, García-Peiro, José Ignacio, Velázquez, David
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2018
País:España
Institución:Universidad de Zaragoza
Repositorio:Zaguán. Repositorio Digital de la Universidad de Zaragoza
OAI Identifier:oai:zaguan.unizar.es:79523
Acceso en línea:http://zaguan.unizar.es/record/79523
Access Level:acceso abierto
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spelling Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysisPires, ElisabetGarcía, José IgnacioLeal-Duaso, AlejandroMayoral, José AntonioGarcía-Peiro, José IgnacioVelázquez, DavidWe present an efficient and green methodology for the synthesis of glycerol monoethers, starting from glycidol and different alcohols, by means of heterogeneous acid catalysis. A scope of Brønsted and Lewis acid catalysts were applied to the benchmark reaction of glycidol and methanol. The selected catalysts were cationic exchangers, such as Nafion NR50, Dowex 50WX2, Amberlyst 15 and K10-Montmorillonite, both in their protonic form and exchanged with Al(III), Zn(II) and Fe(III). Thus, total conversions were reached in short times by using 1 and 5% mol catalyst loading and room temperature, without the need for excess glycidol or the presence of a solvent. Finally, these conditions and the best catalysts were successfully applied to the reaction of glycidol with several alcohols such as butanol or isopropanol.2018info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://zaguan.unizar.es/record/79523reponame:Zaguán. Repositorio Digital de la Universidad de Zaragozainstname:Universidad de ZaragozaInglésinfo:eu-repo/grantAgreement/ES/DGA/E37-17Rinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2014-52367-Rinfo:eu-repo/semantics/openAccessoai:zaguan.unizar.es:795232026-05-29T13:59:51Z
dc.title.none.fl_str_mv Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis
title Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis
spellingShingle Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis
Pires, Elisabet
title_short Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis
title_full Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis
title_fullStr Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis
title_full_unstemmed Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis
title_sort Optimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis
dc.creator.none.fl_str_mv Pires, Elisabet
García, José Ignacio
Leal-Duaso, Alejandro
Mayoral, José Antonio
García-Peiro, José Ignacio
Velázquez, David
author Pires, Elisabet
author_facet Pires, Elisabet
García, José Ignacio
Leal-Duaso, Alejandro
Mayoral, José Antonio
García-Peiro, José Ignacio
Velázquez, David
author_role author
author2 García, José Ignacio
Leal-Duaso, Alejandro
Mayoral, José Antonio
García-Peiro, José Ignacio
Velázquez, David
author2_role author
author
author
author
author
description We present an efficient and green methodology for the synthesis of glycerol monoethers, starting from glycidol and different alcohols, by means of heterogeneous acid catalysis. A scope of Brønsted and Lewis acid catalysts were applied to the benchmark reaction of glycidol and methanol. The selected catalysts were cationic exchangers, such as Nafion NR50, Dowex 50WX2, Amberlyst 15 and K10-Montmorillonite, both in their protonic form and exchanged with Al(III), Zn(II) and Fe(III). Thus, total conversions were reached in short times by using 1 and 5% mol catalyst loading and room temperature, without the need for excess glycidol or the presence of a solvent. Finally, these conditions and the best catalysts were successfully applied to the reaction of glycidol with several alcohols such as butanol or isopropanol.
publishDate 2018
dc.date.none.fl_str_mv 2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://zaguan.unizar.es/record/79523
url http://zaguan.unizar.es/record/79523
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/grantAgreement/ES/DGA/E37-17R
info:eu-repo/grantAgreement/ES/MINECO/CTQ2014-52367-R
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv
publisher.none.fl_str_mv
dc.source.none.fl_str_mv reponame:Zaguán. Repositorio Digital de la Universidad de Zaragoza
instname:Universidad de Zaragoza
instname_str Universidad de Zaragoza
reponame_str Zaguán. Repositorio Digital de la Universidad de Zaragoza
collection Zaguán. Repositorio Digital de la Universidad de Zaragoza
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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