Nickel(II) removal by mixtures of Acorga M5640 and DP8R in pseudo-emulsion based hollow fiber with strip dispersion technology

This work presents the investigation of Ni(II) extraction from aqueous solution through pseudo-emulsion based hollow fiber strip dispersion (PSEHFSD) containing the mixture 2-hydroxy-5-nonylbenzaldehyde oxime + di(2-ethylhexyl) phosphoric acid/Exxsol D100 as extractant in the form of a pseudo-emulsi...

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Detalhes bibliográficos
Autores: González, Roberto, Cerpa, Arisbel, Alguacil, Francisco José
Tipo de documento: artigo
Data de publicação:2010
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/36373
Acesso em linha:http://hdl.handle.net/10261/36373
Access Level:Acceso aberto
Palavra-chave:Nickel(II)
Pseudo-emulsion hollow fiber strip
Dispersion
Acorga M5640
DP8R
Metal transport
Wastewater treatment
Descrição
Resumo:This work presents the investigation of Ni(II) extraction from aqueous solution through pseudo-emulsion based hollow fiber strip dispersion (PSEHFSD) containing the mixture 2-hydroxy-5-nonylbenzaldehyde oxime + di(2-ethylhexyl) phosphoric acid/Exxsol D100 as extractant in the form of a pseudo-emulsion with H2SO4. The organic and aqueous strip phases are separated when the stirring device is stopped. The permeation of Ni(II) is investigated as a function of various experimental variables: hydrodynamic conditions, feed pH, extractants mixture concentration in the pseudo-emulsion, initial Ni(II) concentration in feed phase, H2SO4 concentration in the pseudo-emulsion as strippant. In PEHFSD, pseudo-emulsion is an emulsion that is formed temporarily between organic and stripping solutions. In this investigation, feed was circulated through the lumen side in counter-current mode. The selectivity of 2-hydroxy-5-nonylbenzaldehyde oxime + di(2-ethylhexyl) phosphoric acid/Exxsol D100 based PEHFSD toward different metals was also examined.