Optimization and characterization of reinforced biodegradable cellulose-based aerogels via polylactic acid/polyhydroxybutyrate coating
Vine shoots (VS) and waste eucalyptus paperboard (EP) have been used as cellulose sources (in the form of cellulose nanocrystals -CNCs- and cellulosic fibers respectively) for developing cellulose-based aerogels. Two different parameters including cellulose concentration (0.5 % and 2 % w/v) and free...
| Autores: | , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/338722 |
| Acceso en línea: | http://hdl.handle.net/10261/338722 https://api.elsevier.com/content/abstract/scopus_id/85173137633 |
| Access Level: | acceso abierto |
| Palabra clave: | Biodegradability Cellulosic aerogels PHB PLA Water resistance |
| Sumario: | Vine shoots (VS) and waste eucalyptus paperboard (EP) have been used as cellulose sources (in the form of cellulose nanocrystals -CNCs- and cellulosic fibers respectively) for developing cellulose-based aerogels. Two different parameters including cellulose concentration (0.5 % and 2 % w/v) and freezing temperatures (-20 °C and -80 °C) were tested to evaluate differences in the porosity of the aerogels via Brunauer-Emmett-Teller (BET) and thermal conductivity analyses. In addition, a supplementary coating was applied to the raw aerogels by means of dipping the materials in either polylactic acid (PLA) or polyhydroxybutyrate (PHB) solutions (1 % w/v). Their microstructure was observed via SEM and the reinforcing capacity provided by the coating was measured by means of mechanical compressive tests (~10-fold improvement) and water resistance (contact angle >100°). Finally, aerogels' biodegradability was also confirmed according to the standard ISO 20200 thus providing a sustainable and high-performance alternative to conventional materials also following circular economy principles. |
|---|