Novel Binders for Aqueous Electrode Processing of Electrochemical Capacitors
This work studies the use of epoxy and polyurethane formulations as binders for the aqueous processing of activated carbon (AC) electrodes used as positive and negative electrodes in Electrochemical Double Layer Capacitors (EDLCs). The use of amine and carbodiimide as crosslinkers is also evaluated....
| Autores: | , , , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2025 |
| País: | España |
| Institución: | TECNALIA Research & Innovation |
| Repositorio: | TECNALIA Publications |
| Idioma: | inglés |
| OAI Identifier: | oai:dsp.tecnalia.com:11556/5652 |
| Acceso en línea: | https://hdl.handle.net/11556/5652 |
| Access Level: | acceso abierto |
| Palabra clave: | Aqueous processing Epoxy-amine Flexible supercapacitor Polyurethane Waterborne polymer Environmental Chemistry General Chemical Engineering General Materials Science General Energy |
| Sumario: | This work studies the use of epoxy and polyurethane formulations as binders for the aqueous processing of activated carbon (AC) electrodes used as positive and negative electrodes in Electrochemical Double Layer Capacitors (EDLCs). The use of amine and carbodiimide as crosslinkers is also evaluated. The mechanical properties of those different binders have been investigated, looking towards aqueous processable and flexible electrodes. Microstructural analysis of the fabricated AC electrodes has been carried out to understand the pore-blocking effect exhibited by certain polymers. Furthermore, electrochemical characterization of all the systems has been performed by cyclic voltammetry, electrochemical impedance spectroscopy, and constant current charge/discharge measurements at different current densities. The obtained results show that polyurethane (PU) outperforms in terms of energy and power density the carboxymethyl cellulose:styrene butadiene rubber (CMC : SBR) reference system. Moreover, the studied polyurethanes maintain close to 100 % of their initial capacitance after 2500 cycles under a current density of 5 A g−1 and a discharge time of 20 s. |
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