Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4
Under the terms of the Creative Commons Attribution license.-- et al.
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2016 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/148075 |
| Acceso en línea: | http://hdl.handle.net/10261/148075 |
| Access Level: | acceso abierto |
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Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4Kawaguchi, S.Campo, JavierFabelo, OscarUnder the terms of the Creative Commons Attribution license.-- et al.Using synchrotron and neutron diffraction measurements, we find a low-temperature orthorhombic phase in vanadium spinel FeV2O4. The orbital order of V3+ ions with tetragonal normal modes occurs at 68 K, and this leads to an appearance of the pseudotetragonal phase at a noncollinear ferrimagnetic transition temperature. Below the magnetic transition temperature, unconventional behavior of the orbital state of Fe2+ ions accompanied by the emergence of the orthorhombic phase was observed by using the normal mode analysis. We have also studied the structural properties of orbitally diluted materials. The orthorhombic phase, which is significantly affected by the other ions, is intrinsic in FeV2O4. We suggest the orthorhombic phase is strongly related with the double orbital states of Fe2+ and V3+ ions.This study was supported by the Ministry of Education, Culture, Sports, Science, and Technology of Japan through a Grant-in Aid for Scientific Research and by the Sasagawa Scientific Research Grant from The Japan Science Society.Peer ReviewedAmerican Physical SocietyJapan Society for the Promotion of ScienceMinistry of Education, Culture, Sports, Science and Technology (Japan)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2017201720162017info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/148075reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://dx.doi.org/10.1103/PhysRevB.93.024108Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1480752026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4 |
| title |
Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4 |
| spellingShingle |
Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4 Kawaguchi, S. |
| title_short |
Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4 |
| title_full |
Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4 |
| title_fullStr |
Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4 |
| title_full_unstemmed |
Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4 |
| title_sort |
Orthorhombic distortion and orbital order in the vanadium spinel FeV2 O4 |
| dc.creator.none.fl_str_mv |
Kawaguchi, S. Campo, Javier Fabelo, Oscar |
| author |
Kawaguchi, S. |
| author_facet |
Kawaguchi, S. Campo, Javier Fabelo, Oscar |
| author_role |
author |
| author2 |
Campo, Javier Fabelo, Oscar |
| author2_role |
author author |
| dc.contributor.none.fl_str_mv |
Japan Society for the Promotion of Science Ministry of Education, Culture, Sports, Science and Technology (Japan) Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| description |
Under the terms of the Creative Commons Attribution license.-- et al. |
| publishDate |
2016 |
| dc.date.none.fl_str_mv |
2016 2017 2017 2017 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Publisher's version info:eu-repo/semantics/publishedVersion |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/148075 |
| url |
http://hdl.handle.net/10261/148075 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
http://dx.doi.org/10.1103/PhysRevB.93.024108 Sí |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
American Physical Society |
| publisher.none.fl_str_mv |
American Physical Society |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869403282109104128 |
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15,812429 |