Syntheses, structures, chiroptical and magnetic properties of chiral clusters built from Schiff bases: a novel [MnIIMnIII6NaI2] core

Chiral clusters with MnIIMnIII3NaI and the new MnIIMnIII6NaI2 cores have been synthesised employing enantiomerically pure Schiff bases and halide ligands. The new compounds have been characterized by electronic circular dichroism (ECD) and magnetic susceptibility.

Detalhes bibliográficos
Autores: Escuer Fité, Albert, Mayans Ayats, Júlia, Font Bardia, Ma. Mercedes, Górecki, M., Di Bari, Lorenzo
Tipo de documento: artigo
Estado:Versión aceptada para publicación
Data de publicação:2017
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositório:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/163380
Acesso em linha:https://hdl.handle.net/2445/163380
Access Level:Acceso aberto
Palavra-chave:Quiralitat
Magnetisme
Manganès
Chirality
Magnetism
Manganese
Descrição
Resumo:Chiral clusters with MnIIMnIII3NaI and the new MnIIMnIII6NaI2 cores have been synthesised employing enantiomerically pure Schiff bases and halide ligands. The new compounds have been characterized by electronic circular dichroism (ECD) and magnetic susceptibility.