Pyridine vapors detection by an optical fibre sensor

An optical fibre sensor has been implemented towards pyridine vapors detection; to achieve this, a novel vapochromic material has been used, which, in solid state, suffers a change in colour from blue to pink-white in presence of pyridine vapours. This complex is added to a solution of PVC (Poly Vin...

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Detalles Bibliográficos
Autores: Elosúa Aguado, César, Bariáin Aisa, Cándido, Matías Maestro, Ignacio, Rodríguez, Antonio, Colacio, Enrique, Salinas Castillo, Alfonso, Segura Carretero, Antonio, Fernández Gutiérrez, Alberto
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2008
País:España
Institución:Universidad Pública de Navarra
Repositorio:Academica-e. Repositorio Institucional de la Universidad Pública de Navarra
OAI Identifier:oai:academica-e.unavarra.es:2454/10604
Acceso en línea:https://hdl.handle.net/2454/10604
Access Level:acceso abierto
Palabra clave:Fiber optic sensors
Pyridine vapors sensors
Vapochromic cobalt complex
Dip coating technique
Electronic noses
Sensitivity
Gases
Films
DYE
Descripción
Sumario:An optical fibre sensor has been implemented towards pyridine vapors detection; to achieve this, a novel vapochromic material has been used, which, in solid state, suffers a change in colour from blue to pink-white in presence of pyridine vapours. This complex is added to a solution of PVC (Poly Vinyl Chloride), TBP (Tributylphosphate) and tetrahydrofuran (THF), forming a plasticized matrix; by dip coating technique, the sensing material is fixed onto a cleaved ended optical fibre. The fabrication process was optimized in terms of number of dips and dipping speed, evaluating the final devices by dynamic range. Employing a reflection set up, the absorbance spectra and changes in the reflected optical power of the sensors were registered to determine their response. A linear relation between optical power versus vapor concentration was obtained, with a detection limit of 1 ppm (v/v).