A C60‐aryne building block: Synthesis of a hybrid all‐carbon nanostructure

The synthesis of a [60]fullerene‐benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all‐carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the f...

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Detalles Bibliográficos
Autores: García, D., Herranz, M.Angeles, Rodríguez Pérez, Laura, Peña, D., Guitián, E., Bailey, S., Al-Galiby, Q., Noori, M., Lambert, C.J., Pérez, D., Martín, Nazario
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/23486
Acceso en línea:https://hdl.handle.net/20.500.14352/23486
Access Level:acceso abierto
Palabra clave:547
Química orgánica (Química)
2306 Química Orgánica
Descripción
Sumario:The synthesis of a [60]fullerene‐benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all‐carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible.