Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalability

Membrane technology has attracted great industrial interest in carbon capture and separation owing to the merits of energy-efficiency, environmental friendliness and low capital investment. Conventional polymeric membranes for CO2 separation suffer from the trade-off between permeability and selecti...

Descripción completa

Detalles Bibliográficos
Autores: Shan, Meixia, Geng, Xiumei, Imaz, Inhar, Broto-Ribas, Anna, Ortín-Rubio, Borja, Maspoch, Daniel, Ansaloni, Luca, Peters, Thijs A., Tena, Alberto, Boerrigter, Marcel E., Vermaas, David A.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/356704
Acceso en línea:http://hdl.handle.net/10261/356704
Access Level:acceso abierto
id ES_0a683de0f57f3370326569e2fed65f0b
oai_identifier_str oai:digital.csic.es:10261/356704
network_acronym_str ES
network_name_str España
repository_id_str
spelling Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalabilityShan, MeixiaGeng, XiumeiImaz, InharBroto-Ribas, AnnaOrtín-Rubio, BorjaMaspoch, DanielAnsaloni, LucaPeters, Thijs A.Tena, AlbertoBoerrigter, Marcel E.Vermaas, David A.Membrane technology has attracted great industrial interest in carbon capture and separation owing to the merits of energy-efficiency, environmental friendliness and low capital investment. Conventional polymeric membranes for CO2 separation suffer from the trade-off between permeability and selectivity. Introducing porous fillers in polymers is one approach to enhance membrane separation performance. Metal-organic frameworks (MOFs), with ordered porous structure and diverse chemical functionalities, are promising fillers to prepare mixed matrix membranes (MMMs) for CO2 separation. However, the main issue of MOF based MMMs in industry is their stability and processability. This review analyses recent work on stable and scalable MOF based MMMs for CO2 separation. The typical stable MOFs, MOF-based MMMs and the scalable MOF synthesis are summarized. A large number of MOF-based MMM suffer from instability upon exposure to contaminants. For that reason, we also discuss the use of covalent organic frameworks (COFs) as an alternative to prepare MMMs for CO2 separation, considering their excellent stability and good compatibility with polymers. Finally, a brief conclusion and current challenges on obtaining scalable and stable MMMs are outlined. This review may provide some guidance for designing high performance MMMs for industrial CO2 capture and separation to help achieving carbon neutrality.The authors acknowledge financial support from the European Union's Horizon 2020 research and innovation program under grant agreement No 760899, the National Natural Science Foundation of China (Nos. 52003250) and China Postdoctoral Science Foundation (No. 2020M682351). This work was also supported by the Catalan AGAUR (project 2017 SGR 238) and the CERCA Program/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa program from the Spanish MINECO (grant SEV-2017-0706).Peer reviewedElsevierEuropean CommissionGeneralitat de CatalunyaChina Postdoctoral Science FoundationNational Natural Science Foundation of ChinaConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202420242024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/356704reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/H2020/760899info:eu-repo/grantAgreement/AEI//SEV-2017-0706https://doi.org/10.1016/j.memsci.2023.122258Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3567042026-05-22T06:33:51Z
dc.title.none.fl_str_mv Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalability
title Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalability
spellingShingle Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalability
Shan, Meixia
title_short Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalability
title_full Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalability
title_fullStr Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalability
title_full_unstemmed Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalability
title_sort Metal- and covalent-organic framework mixed matrix membranes for CO2 separation: A perspective on stability and scalability
dc.creator.none.fl_str_mv Shan, Meixia
Geng, Xiumei
Imaz, Inhar
Broto-Ribas, Anna
Ortín-Rubio, Borja
Maspoch, Daniel
Ansaloni, Luca
Peters, Thijs A.
Tena, Alberto
Boerrigter, Marcel E.
Vermaas, David A.
author Shan, Meixia
author_facet Shan, Meixia
Geng, Xiumei
Imaz, Inhar
Broto-Ribas, Anna
Ortín-Rubio, Borja
Maspoch, Daniel
Ansaloni, Luca
Peters, Thijs A.
Tena, Alberto
Boerrigter, Marcel E.
Vermaas, David A.
author_role author
author2 Geng, Xiumei
Imaz, Inhar
Broto-Ribas, Anna
Ortín-Rubio, Borja
Maspoch, Daniel
Ansaloni, Luca
Peters, Thijs A.
Tena, Alberto
Boerrigter, Marcel E.
Vermaas, David A.
author2_role author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv European Commission
Generalitat de Catalunya
China Postdoctoral Science Foundation
National Natural Science Foundation of China
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description Membrane technology has attracted great industrial interest in carbon capture and separation owing to the merits of energy-efficiency, environmental friendliness and low capital investment. Conventional polymeric membranes for CO2 separation suffer from the trade-off between permeability and selectivity. Introducing porous fillers in polymers is one approach to enhance membrane separation performance. Metal-organic frameworks (MOFs), with ordered porous structure and diverse chemical functionalities, are promising fillers to prepare mixed matrix membranes (MMMs) for CO2 separation. However, the main issue of MOF based MMMs in industry is their stability and processability. This review analyses recent work on stable and scalable MOF based MMMs for CO2 separation. The typical stable MOFs, MOF-based MMMs and the scalable MOF synthesis are summarized. A large number of MOF-based MMM suffer from instability upon exposure to contaminants. For that reason, we also discuss the use of covalent organic frameworks (COFs) as an alternative to prepare MMMs for CO2 separation, considering their excellent stability and good compatibility with polymers. Finally, a brief conclusion and current challenges on obtaining scalable and stable MMMs are outlined. This review may provide some guidance for designing high performance MMMs for industrial CO2 capture and separation to help achieving carbon neutrality.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/356704
url http://hdl.handle.net/10261/356704
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/H2020/760899
info:eu-repo/grantAgreement/AEI//SEV-2017-0706
https://doi.org/10.1016/j.memsci.2023.122258
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869403162049249280
score 15,81155

Similares en LA Referencia