Enhancement of the Magnetic Refrigerant Capacity in Partially Amorphous Fe 70Zr 30 Powders Obtained by Mechanical Alloying
After mechanical alloying Fe 70Zr 30 composition from pure starting powders, an amorphous phase with Curie temperature T C = 244 K and an intermetallic compound (that should be non-stoichiometric Zr-rich fcc Fe 2Zr phase) with T C = 355 K are formed. Residual α-Fe crystallites are also found. The mu...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2012 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/147173 |
| Acceso en línea: | https://hdl.handle.net/11441/147173 https://doi.org/10.1016/j.intermet.2012.03.011 |
| Access Level: | acceso abierto |
| Palabra clave: | Magnetic intermetallics Nanostructured intermetallics Magnetic properties Mechanical alloying and milling |
| Sumario: | After mechanical alloying Fe 70Zr 30 composition from pure starting powders, an amorphous phase with Curie temperature T C = 244 K and an intermetallic compound (that should be non-stoichiometric Zr-rich fcc Fe 2Zr phase) with T C = 355 K are formed. Residual α-Fe crystallites are also found. The multiphase character of this system yields a non-monotonic dependence of the magnetocaloric effect (characterized by the refrigerant capacity, RC) on the fraction of phases. Among the samples studied in this work, RC is enhanced for samples with the highest fraction of intermetallic compound, although the maximum magnetic entropy change monotonically decreases with the increase of the fraction of this phase. This behaviour agrees with the predicted one for biphasic systems. |
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