Effective fixation of CO2 by iridium-catalyzed hydrosilylation

CO2 as feedstock: An air- and moisture-stable iridium(III) catalyst effectively promotes the hydrosilylation of CO2. This reaction leads to silyl formate in a highly selective manner and proceeds efficiently under mild conditions, most likely by an outer-sphere mechanism, as suggested by theoretical...

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Detalles Bibliográficos
Autores: Lalrempuia, Ralte, Iglesias, Manuel, Polo, Víctor, Sanz Miguel, Pablo J., Fernández-Álvarez, Francisco J., Pérez-Torrente, Jesús J., Oro, Luis A.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2012
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/64582
Acceso en línea:http://hdl.handle.net/10261/64582
Access Level:acceso abierto
Descripción
Sumario:CO2 as feedstock: An air- and moisture-stable iridium(III) catalyst effectively promotes the hydrosilylation of CO2. This reaction leads to silyl formate in a highly selective manner and proceeds efficiently under mild conditions, most likely by an outer-sphere mechanism, as suggested by theoretical calculations. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.