Neutral and cationic pentafluorophenylnickel(II) complexes
Metathetical reactions of Br(C6F5)Ni(PPh3)2 with metal salts MX (NaI, NaNO2, NaNO3, KCN, KSCN, AgClO4) have given the corresponding X(C6F5)Ni(PPh3)2 complexes. The perchlorate group of the complex (O3ClO)Ni(C6F5)(PPh3)2 is readily displaced. In this way cationic complexes [(C6F5)Ni(PPh3)2L]ClO4 have...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 1977 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4891 |
| Acceso en línea: | http://hdl.handle.net/10017/4891 https://dx.doi.org/10.1016/S0022-328X(00)83530-5 |
| Access Level: | acceso abierto |
| Palabra clave: | Pentafluorophenylnickel(II) complexes Ciencia Química inorgánica Science Chemistry, inorganic |
| Sumario: | Metathetical reactions of Br(C6F5)Ni(PPh3)2 with metal salts MX (NaI, NaNO2, NaNO3, KCN, KSCN, AgClO4) have given the corresponding X(C6F5)Ni(PPh3)2 complexes. The perchlorate group of the complex (O3ClO)Ni(C6F5)(PPh3)2 is readily displaced. In this way cationic complexes [(C6F5)Ni(PPh3)2L]ClO4 have been prepared with L --- PPh3, PEt3, P-t-Bu3, AsPh3, C5H5N, OPPh3, SPPh3, H2O, or CH3NO2. |
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