Optical constants of NH3 and NH3:N2 amorphous ices in the near-infrared and mid-infrared regions

Ammonia ice has been detected on different astrophysical media ranging from interstellar medium (ISM) particles to the surface of various icy bodies of our solar system, where nitrogen is also present. We have carried out a detailed study of amorphous NH3 ice and NH3:N2 ice mixtures, based on infrar...

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Bibliographic Details
Authors: Zanchet, Alexandre, Rodríguez Lazcano, Yamilet, Gálvez, Óscar, Herrero, Víctor J., Escribano, Rafael, Maté, Belén
Format: article
Publication Date:2013
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:dnet:digitalcsic_::09ddae3bfb876264d1921994f445d630
Online Access:http://hdl.handle.net/10261/89559
Access Level:Open access
Keyword:methods: laboratory: solid state
planets and satellites: composition
techniques: spectroscopic
ISM: abundances
Description
Summary:Ammonia ice has been detected on different astrophysical media ranging from interstellar medium (ISM) particles to the surface of various icy bodies of our solar system, where nitrogen is also present. We have carried out a detailed study of amorphous NH3 ice and NH3:N2 ice mixtures, based on infrared (IR) spectra in the mid-IR (MIR) and near-IR (NIR) regions, supported by theoretical quantum chemical calculations. Spectra of varying ice thicknesses were obtained and optical constants were calculated for amorphous NH3 at 15 K and 30 K and for a NH3:N2 mixture at 15 K over a 500-7000 cm-1 spectral range. These spectra have improved accuracy over previous data, where available. Moreover, we also obtained absolute values for the band strengths of the more prominent IR features in both spectral regions. Our results indicate that the estimated NH3 concentration in ISM ices should be scaled upward by 30%. © 2013. The American Astronomical Society. All rights reserved.