Synthesis and catalytic activity of Ti-ITQ-7: a new oxidation catalyst with a three dimensional system of large pore channels

Isomorphous substitution of Si by Ti in the framework of ITQ-7, the crystalline silica polymorph of lowest density, has been achieved by direct synthesis, affording its three dimensional system of large pore channels to be used in selective oxidation reactions.

Detalles Bibliográficos
Autores: Díaz Cabañas, María José, Villaescusa, Luis A., Camblor, Miguel Ángel
Tipo de recurso: artículo
Fecha de publicación:2000
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/7821
Acceso en línea:http://hdl.handle.net/10261/7821
Access Level:acceso abierto
Palabra clave:Zeolites
Ti-zeolites
selective oxidation catalyst
Ti-ITQ-7
Large pore
ISV
olefins epoxidation
Isomorphous substitution
Descripción
Sumario:Isomorphous substitution of Si by Ti in the framework of ITQ-7, the crystalline silica polymorph of lowest density, has been achieved by direct synthesis, affording its three dimensional system of large pore channels to be used in selective oxidation reactions.