Switchable Fe/Co Prussian blue networks and molecular analogues

With the long term objective to build the next generation of devices from the molecular scale, scientists have explored extensively in the past two decades the Prussian blue derivatives and their remarkable physico-chemical properties. In particular, the exquisite Fe/Co system displays tuneable opti...

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Detalles Bibliográficos
Autores: Aguilà Avilés, David, Prado, Yoann, Koumousi, Evangelia S., Mathonière, Corine, Clérac, Rodolphe
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/158576
Acceso en línea:https://hdl.handle.net/2445/158576
Access Level:acceso abierto
Palabra clave:Camps magnètics
Magnetoquímica
Magnetic fields
Magnetochemistry
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spelling Switchable Fe/Co Prussian blue networks and molecular analoguesAguilà Avilés, DavidPrado, YoannKoumousi, Evangelia S.Mathonière, CorineClérac, RodolpheCamps magnèticsMagnetoquímicaMagnetic fieldsMagnetochemistryWith the long term objective to build the next generation of devices from the molecular scale, scientists have explored extensively in the past two decades the Prussian blue derivatives and their remarkable physico-chemical properties. In particular, the exquisite Fe/Co system displays tuneable optical and magnetic behaviours associated with thermally and photo-induced metal-to-metal electron transfer processes. Recently, numerous research groups have been involved in the transfer of these electronic properties to new Fe/Co coordination networks of lower dimensionality as well as soluble molecular analogues in order to facilitate their manipulation and integration into devices. In this review, the most representative examples of tridimensional Fe/Co Prussian blue compounds are described, focusing on the techniques used to understand their photomagnetic properties. Subsequently, the different strategies employed toward the design of new low dimensional Prussian blue analogues based on a rational molecular building block approach are discussed emphasizing the advantages of these functional molecular systems.Royal Society of Chemistry2020202020152020info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion22 p.application/pdfhttps://hdl.handle.net/2445/158576Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésVersió postprint del document publicat a: https://doi.org/10.1039/c5cs00321kChemical Society Reviews, 2015, vol. 45, p. 203-224https://doi.org/10.1039/c5cs00321kcc by (c) Aguilà Avilés, David et al., 2015http://creativecommons.org/licenses/by-nc/3.0/es/info:eu-repo/semantics/openAccessoai:recercat.cat:2445/1585762026-05-29T05:05:01Z
dc.title.none.fl_str_mv Switchable Fe/Co Prussian blue networks and molecular analogues
title Switchable Fe/Co Prussian blue networks and molecular analogues
spellingShingle Switchable Fe/Co Prussian blue networks and molecular analogues
Aguilà Avilés, David
Camps magnètics
Magnetoquímica
Magnetic fields
Magnetochemistry
title_short Switchable Fe/Co Prussian blue networks and molecular analogues
title_full Switchable Fe/Co Prussian blue networks and molecular analogues
title_fullStr Switchable Fe/Co Prussian blue networks and molecular analogues
title_full_unstemmed Switchable Fe/Co Prussian blue networks and molecular analogues
title_sort Switchable Fe/Co Prussian blue networks and molecular analogues
dc.creator.none.fl_str_mv Aguilà Avilés, David
Prado, Yoann
Koumousi, Evangelia S.
Mathonière, Corine
Clérac, Rodolphe
author Aguilà Avilés, David
author_facet Aguilà Avilés, David
Prado, Yoann
Koumousi, Evangelia S.
Mathonière, Corine
Clérac, Rodolphe
author_role author
author2 Prado, Yoann
Koumousi, Evangelia S.
Mathonière, Corine
Clérac, Rodolphe
author2_role author
author
author
author
dc.subject.none.fl_str_mv Camps magnètics
Magnetoquímica
Magnetic fields
Magnetochemistry
topic Camps magnètics
Magnetoquímica
Magnetic fields
Magnetochemistry
description With the long term objective to build the next generation of devices from the molecular scale, scientists have explored extensively in the past two decades the Prussian blue derivatives and their remarkable physico-chemical properties. In particular, the exquisite Fe/Co system displays tuneable optical and magnetic behaviours associated with thermally and photo-induced metal-to-metal electron transfer processes. Recently, numerous research groups have been involved in the transfer of these electronic properties to new Fe/Co coordination networks of lower dimensionality as well as soluble molecular analogues in order to facilitate their manipulation and integration into devices. In this review, the most representative examples of tridimensional Fe/Co Prussian blue compounds are described, focusing on the techniques used to understand their photomagnetic properties. Subsequently, the different strategies employed toward the design of new low dimensional Prussian blue analogues based on a rational molecular building block approach are discussed emphasizing the advantages of these functional molecular systems.
publishDate 2015
dc.date.none.fl_str_mv 2015
2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/158576
url https://hdl.handle.net/2445/158576
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1039/c5cs00321k
Chemical Society Reviews, 2015, vol. 45, p. 203-224
https://doi.org/10.1039/c5cs00321k
dc.rights.none.fl_str_mv cc by (c) Aguilà Avilés, David et al., 2015
http://creativecommons.org/licenses/by-nc/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc by (c) Aguilà Avilés, David et al., 2015
http://creativecommons.org/licenses/by-nc/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 22 p.
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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