Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of Methane

Dry reforming of methane (DRM) represents an alluring approach to the direct conversion of CO2 and CH4, gases with the highest global warming potential, into syngas, a value-added intermediate used in chemical industry. In this study, mixed oxide structures of cerium and zirconium doped with 10 wt%...

Descripción completa

Detalles Bibliográficos
Autores: Martín Espejo, Juan Luis, Merkouri, Loukia Pantzechroula, Odriozola Gordón, José Antonio, Ramírez Reina, Tomás, Pastor Pérez, Laura
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/169582
Acceso en línea:https://hdl.handle.net/11441/169582
https://doi.org/10.1016/j.ceramint.2024.07.205
Access Level:acceso abierto
Palabra clave:Calcination A
Dry reforming of methane
Perovskites D
id ES_06eba4682b0481b7ef4c6ea3eaab6fae
oai_identifier_str oai:idus.us.es:11441/169582
network_acronym_str ES
network_name_str España
repository_id_str
spelling Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of MethaneMartín Espejo, Juan LuisMerkouri, Loukia PantzechroulaOdriozola Gordón, José AntonioRamírez Reina, TomásPastor Pérez, LauraCalcination ADry reforming of methanePerovskites DDry reforming of methane (DRM) represents an alluring approach to the direct conversion of CO2 and CH4, gases with the highest global warming potential, into syngas, a value-added intermediate used in chemical industry. In this study, mixed oxide structures of cerium and zirconium doped with 10 wt% Ni were used due to the high thermal stability. This study showcased the importance of choosing suitable conditions and explored the impact of calcination temperature on Ce–Zr mixed oxides with Ni. XRD analysis confirmed the existence of different crystalline phases according to the calcination temperature. Redox characterisation showed a trade-off among calcination temperature, the dispersion of Ni clusters and its interaction with the support structure. Calcined catalysts at 900 and 1000 °C underwent harsh, long-term DRM conditions. Despite the low surface area of the designed catalysts, the stability experiments proved a relation between dispersion of Ni active phase and catalytic performance, showing an optimum calcination temperature of 1000 °C.Ministerio de Ciencia e Innovación PID2019-108502RJ-I00, IJC2019-040560-I, RYC2018-024387-IElsevierQuímica InorgánicaMinisterio de Ciencia e Innovación (MICIN). España2024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/169582https://doi.org/10.1016/j.ceramint.2024.07.205reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésCeramics International, 50 (20), 38406-38414.PID2019-108502RJ-I00IJC2019-040560-IRYC2018-024387-Ihttps://doi.org/10.1016/j.ceramint.2024.07.205info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1695822026-06-17T12:51:07Z
dc.title.none.fl_str_mv Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of Methane
title Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of Methane
spellingShingle Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of Methane
Martín Espejo, Juan Luis
Calcination A
Dry reforming of methane
Perovskites D
title_short Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of Methane
title_full Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of Methane
title_fullStr Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of Methane
title_full_unstemmed Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of Methane
title_sort Effect of Calcination Temperature on the Synthesis of Ni-based Cerium Zirconate for Dry Reforming of Methane
dc.creator.none.fl_str_mv Martín Espejo, Juan Luis
Merkouri, Loukia Pantzechroula
Odriozola Gordón, José Antonio
Ramírez Reina, Tomás
Pastor Pérez, Laura
author Martín Espejo, Juan Luis
author_facet Martín Espejo, Juan Luis
Merkouri, Loukia Pantzechroula
Odriozola Gordón, José Antonio
Ramírez Reina, Tomás
Pastor Pérez, Laura
author_role author
author2 Merkouri, Loukia Pantzechroula
Odriozola Gordón, José Antonio
Ramírez Reina, Tomás
Pastor Pérez, Laura
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Química Inorgánica
Ministerio de Ciencia e Innovación (MICIN). España
dc.subject.none.fl_str_mv Calcination A
Dry reforming of methane
Perovskites D
topic Calcination A
Dry reforming of methane
Perovskites D
description Dry reforming of methane (DRM) represents an alluring approach to the direct conversion of CO2 and CH4, gases with the highest global warming potential, into syngas, a value-added intermediate used in chemical industry. In this study, mixed oxide structures of cerium and zirconium doped with 10 wt% Ni were used due to the high thermal stability. This study showcased the importance of choosing suitable conditions and explored the impact of calcination temperature on Ce–Zr mixed oxides with Ni. XRD analysis confirmed the existence of different crystalline phases according to the calcination temperature. Redox characterisation showed a trade-off among calcination temperature, the dispersion of Ni clusters and its interaction with the support structure. Calcined catalysts at 900 and 1000 °C underwent harsh, long-term DRM conditions. Despite the low surface area of the designed catalysts, the stability experiments proved a relation between dispersion of Ni active phase and catalytic performance, showing an optimum calcination temperature of 1000 °C.
publishDate 2024
dc.date.none.fl_str_mv 2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/169582
https://doi.org/10.1016/j.ceramint.2024.07.205
url https://hdl.handle.net/11441/169582
https://doi.org/10.1016/j.ceramint.2024.07.205
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Ceramics International, 50 (20), 38406-38414.
PID2019-108502RJ-I00
IJC2019-040560-I
RYC2018-024387-I
https://doi.org/10.1016/j.ceramint.2024.07.205
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869402947232727040
score 15.811543

Similares en LA Referencia