Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes

Microwave assisted synthesis and bench-top reactions are compared for Mn and Mn/Ni reaction systems with substituted salicylic acid (2-hydroxy-6-isopropyl-3-methylbenzoic-acid (SALOH2). When Mn salts are used, the microwave assisted synthesis and the bench-top reaction afford the same product: the n...

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Autores: Ledezma Gairaud, Marisol, Pineda, L.W., Aromí Bedmar, Guillem, Sañudo Zotes, Eva Carolina
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2015
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/154388
Acceso en línea:https://hdl.handle.net/2445/154388
Access Level:acceso abierto
Palabra clave:Lligands
Propietats magnètiques
Ligands
Magnetic properties
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spelling Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexesLedezma Gairaud, MarisolPineda, L.W.Aromí Bedmar, GuillemSañudo Zotes, Eva CarolinaLligandsPropietats magnètiquesLigandsMagnetic propertiesMicrowave assisted synthesis and bench-top reactions are compared for Mn and Mn/Ni reaction systems with substituted salicylic acid (2-hydroxy-6-isopropyl-3-methylbenzoic-acid (SALOH2). When Mn salts are used, the microwave assisted synthesis and the bench-top reaction afford the same product: the new octanuclear Mn(II)/Mn(III) complex [Mn8O2(OMe)2Cl2(SALO)6(MeOH)4(H2O)2] (1). However, in a mixed metal Mn/Ni reaction the bench-top reaction results in the new heterometallic distorted cubane complexes [Pr2NH2][Mn2Ni2(OH)2(L1)2(SALO)2(SALOH)3] (where L1H = 3-dimethylamino-1-propanol), (2) and [Pr2NH2][Mn2Ni2(OH)(OMe)2(L1)(MeCN)(SALO)2(SALOH)3] (3). The crystal structure and magnetic properties of the prepared complexes are presented.Elsevier B.V.2020202020152020info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersion6 p.application/pdfhttps://hdl.handle.net/2445/154388Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésVersió postprint del document publicat a: https://doi.org/10.1016/j.ica.2015.05.030Inorganica Chimica Acta, 2015, vol. 434, p. 215-220https://doi.org/10.1016/j.ica.2015.05.030cc-by (c) Mognon, Lorenzo et al.http://creativecommons.org/licenses/by/3.0/es/info:eu-repo/semantics/openAccessoai:recercat.cat:2445/1543882026-05-29T05:05:01Z
dc.title.none.fl_str_mv Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
title Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
spellingShingle Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
Ledezma Gairaud, Marisol
Lligands
Propietats magnètiques
Ligands
Magnetic properties
title_short Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
title_full Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
title_fullStr Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
title_full_unstemmed Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
title_sort Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
dc.creator.none.fl_str_mv Ledezma Gairaud, Marisol
Pineda, L.W.
Aromí Bedmar, Guillem
Sañudo Zotes, Eva Carolina
author Ledezma Gairaud, Marisol
author_facet Ledezma Gairaud, Marisol
Pineda, L.W.
Aromí Bedmar, Guillem
Sañudo Zotes, Eva Carolina
author_role author
author2 Pineda, L.W.
Aromí Bedmar, Guillem
Sañudo Zotes, Eva Carolina
author2_role author
author
author
dc.subject.none.fl_str_mv Lligands
Propietats magnètiques
Ligands
Magnetic properties
topic Lligands
Propietats magnètiques
Ligands
Magnetic properties
description Microwave assisted synthesis and bench-top reactions are compared for Mn and Mn/Ni reaction systems with substituted salicylic acid (2-hydroxy-6-isopropyl-3-methylbenzoic-acid (SALOH2). When Mn salts are used, the microwave assisted synthesis and the bench-top reaction afford the same product: the new octanuclear Mn(II)/Mn(III) complex [Mn8O2(OMe)2Cl2(SALO)6(MeOH)4(H2O)2] (1). However, in a mixed metal Mn/Ni reaction the bench-top reaction results in the new heterometallic distorted cubane complexes [Pr2NH2][Mn2Ni2(OH)2(L1)2(SALO)2(SALOH)3] (where L1H = 3-dimethylamino-1-propanol), (2) and [Pr2NH2][Mn2Ni2(OH)(OMe)2(L1)(MeCN)(SALO)2(SALOH)3] (3). The crystal structure and magnetic properties of the prepared complexes are presented.
publishDate 2015
dc.date.none.fl_str_mv 2015
2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/154388
url https://hdl.handle.net/2445/154388
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1016/j.ica.2015.05.030
Inorganica Chimica Acta, 2015, vol. 434, p. 215-220
https://doi.org/10.1016/j.ica.2015.05.030
dc.rights.none.fl_str_mv cc-by (c) Mognon, Lorenzo et al.
http://creativecommons.org/licenses/by/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by (c) Mognon, Lorenzo et al.
http://creativecommons.org/licenses/by/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 6 p.
application/pdf
dc.publisher.none.fl_str_mv Elsevier B.V.
publisher.none.fl_str_mv Elsevier B.V.
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,81155

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