Accurate Frequency Determination of Vibration–Rotation and Rotational Transitions of SiH+

The fundamental 28SiH+ ion has been characterized in a collaborative work, utilizing a hollow-cathode discharge laser spectrometer and a cryogenic ion trap spectrometer. Twenty-three vibration–rotation transitions around 4.75 μm have been detected with high accuracy. This has facilitated the first d...

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Detalhes bibliográficos
Autores: Doménech, José Luis, Schlemmer, Stephan, Asvany, Oskar
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2017
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/156960
Acesso em linha:http://hdl.handle.net/10261/156960
Access Level:acceso abierto
Palavra-chave:ISM: molecules
Methods: laboratory: molecular
Molecular data
Techniques: spectroscopic
Descrição
Resumo:The fundamental 28SiH+ ion has been characterized in a collaborative work, utilizing a hollow-cathode discharge laser spectrometer and a cryogenic ion trap spectrometer. Twenty-three vibration–rotation transitions around 4.75 μm have been detected with high accuracy. This has facilitated the first direct measurement of the pure rotational transition J = 1 - 0 at 453056.3632(4) MHz in the trap spectrometer. The measured and accurately predicted transitions enable the search for this ion in space with IR and sub-mm telescopes.