Supporting Information for Mesoporous Sn-In-MCM-41 catalysts for the selective sugar conversion to methyl lactate and comparative life cycle assessment with the biochemical process

TGA curves of Sn-In-MCM-41: as synthesized, calcined, and after four catalytic cycles; XRD patterns of as-synthesized and calcined Sn-In-MCM-41; XRD patterns of as-synthesized and calcined In-MCM-41; FTIR spectra of calcined Sn-In-MCM-41, Sn-MCM-41, and In-MCM-41; FTIR spectra of Sn-In-MCM-41, Sn-MC...

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Detalhes bibliográficos
Autores: Iglesia, Óscar de la, Sarango, Miryam, Munárriz, Mikel, Malankowska, Magdalena, Navajas, Alberto, Gandía, Luis M., Coronas, Joaquín, Téllez, Carlos
Tipo de documento: conjunto de datos
Data de publicação:2022
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/329489
Acesso em linha:http://hdl.handle.net/10261/329489
Access Level:Acceso aberto
Descrição
Resumo:TGA curves of Sn-In-MCM-41: as synthesized, calcined, and after four catalytic cycles; XRD patterns of as-synthesized and calcined Sn-In-MCM-41; XRD patterns of as-synthesized and calcined In-MCM-41; FTIR spectra of calcined Sn-In-MCM-41, Sn-MCM-41, and In-MCM-41; FTIR spectra of Sn-In-MCM-41, Sn-MCM-41, and In-MCM-41 before and after pyridine adsorption and heating at 353 K; nitrogen adsorption–desorption isotherms of Sn-In-MCM-41, Sn-MCM-41, and In-MCM-41; BJH adsorption of Sn-In-MCM-41, Sn-MCM-41, and In-MCM-41; complete XPS spectra of Sn-In-MCM-41 fresh and after four catalytic cycles, Sn-MCM-41, and In-MCM-41; XPS spectra of Sn-MCM-41 fresh and after four catalytic cycles; catalytic results obtained for sugar conversion with Sn-In-MCM-41 in catalytic cycles (160 °C for 20 h, 160 mg of catalyst, and 225 mg of glucose); reaction mechanism; inputs for the LCA calculations on GaBi Software; flowchart for the production of 1 kg of glucose (Ecoinvent); environmental impact indicators (EIIs), units, and recommendation level; environmental impact indicator values; and contribution of the different processes to the EII values for the biochemical and chemical routes.