Bimetallic PdAu catalysts for formic acid dehydrogenation
A series of monometallic and bimetallic palladium gold catalyst were prepared and studied for the formic acid dehydrogenation reaction. Different Pd/Au compositions were employed (PdAu, where x = 25; 50 and 75) and their impact on alloy structure, particle size and dispersion was evaluated. Active p...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2020 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/219640 |
| Acceso en línea: | http://hdl.handle.net/10261/219640 |
| Access Level: | acceso abierto |
| Palabra clave: | Formic Acid dehydrogenation Hydrogen economy Palladium Gold Bimetallic catalysts |
| Sumario: | A series of monometallic and bimetallic palladium gold catalyst were prepared and studied for the formic acid dehydrogenation reaction. Different Pd/Au compositions were employed (PdAu, where x = 25; 50 and 75) and their impact on alloy structure, particle size and dispersion was evaluated. Active phase composition and reaction parameters such as temperature, formic acid concentration or formate/formic acid ratio were adjusted to obtain active and selective catalyst for hydrogen production. An important particle size effect was observed and related to Pd/Au composition for all bimetallic catalysts. |
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