Towards sustainable solid-state supercapacitors: Electroactive conducting polymers combined with biohydrogels
Solid-state organic electrochemical supercapacitors (OESCs) have been fabricated using poly(3,4-ethylenedioxythiophene) (PEDOT) electrodes, a biohydrogel as electrolyte system, and polyaniline fibers as redox additive. The effectivity of sodium alginate, κ-carrageenan, chitosan and gelatin hydrogels...
| Authors: | , , , , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2016 |
| Country: | España |
| Institution: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repository: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/178064 |
| Online Access: | http://hdl.handle.net/10261/178064 |
| Access Level: | Open access |
| Keyword: | Polyaniline Polypyrroles Supercapacitor electrode Capacitors Conducting polymers |
| Summary: | Solid-state organic electrochemical supercapacitors (OESCs) have been fabricated using poly(3,4-ethylenedioxythiophene) (PEDOT) electrodes, a biohydrogel as electrolyte system, and polyaniline fibers as redox additive. The effectivity of sodium alginate, κ-carrageenan, chitosan and gelatin hydrogels as electrolytic media has been evaluated considering different criteria. Results indicate that κ-carrageenan-based hydrogel is the most suitable to perform as electrolyte due to the appropriate combination of properties: mechanical stability, ease of preparation, lack of water leaking, and good medium for the electrochemical response of PEDOT electrodes. Cyclic voltammetry and galvanostatic charge-discharge assays indicate that OESCs based on PEDOT electrodes and κ-carrageenan hydrogel as electrolyte exhibits a good supercapacitor response in terms of specific capacitance, cycling stability, small leakage current and low self-discharging tendency. On the basis of these good properties, four OESC devices were assembled in series and used to power a red LED, confirming that, in addition to advantageous characteristics (e.g. elimination of liquid leaking and enhancement of the device compactness), the designed biohydrogel-containing OESC exhibits potential for practical applications. On the other hand, preliminary assays have been performed loading the κ-carrageenan hydrogel with polyaniline nanofibers, which act as a redox additive. OESC devices prepared using such loaded biohydrogel have been found to be very promising and, therefore, future work is oriented towards the improvement of their design. © The Royal Society of Chemistry 2016. |
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