Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction data

This is an open-access article distributed under the terms of the Creative Commons Attribution Licence.

Detalles Bibliográficos
Autores: Mtioui-Sghaier, Olfa, Mendoza-Meroño, Rafael, Ktari, Lilia, Dammak, Mohamed, García-Granda, Santiago
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/137469
Acceso en línea:http://hdl.handle.net/10261/137469
Access Level:acceso abierto
Palabra clave:Crystal structures
Redetermination
Wolframite structure type
Hydro­thermal synthesis
β-ZnMoO4
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spelling Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction dataMtioui-Sghaier, OlfaMendoza-Meroño, RafaelKtari, LiliaDammak, MohamedGarcía-Granda, SantiagoCrystal structuresRedeterminationWolframite structure typeHydro­thermal synthesisβ-ZnMoO4This is an open-access article distributed under the terms of the Creative Commons Attribution Licence.The crystal structure of the β-polymorph of ZnMoO4 was re-determined on the basis of single-crystal X-ray diffraction data. In comparison with previous powder X-ray diffraction studies [Katikaneani & Arunachalam (2005 ▸). Eur. J. Inorg. Chem. pp. 3080–3087; Cavalcante et al. (2013 ▸). Polyhedron, 54, 13–25], all atoms were refined with anisotropic displacement parameters, leading to a higher precision with respect to bond lengths and angles. β-ZnMoO4 adopts the wolframite structure type and is composed of distorted ZnO6 and MoO6 octa­hedra, both with point group symmetry 2. The distortion of the octa­hedra is reflected by variation of bond lengths and angles from 2.002 (3)–2.274 (4) Å, 80.63 (11)–108.8 (2)° for equatorial and 158.4 (2)– 162.81 (14)° for axial angles (ZnO6), and of 1.769 (3)–2.171 (3) Å, 73.39 (16)–104.7 (2), 150.8 (2)–164.89 (15)° (MoO6), respectively. In the crystal structure, the same type of MO6 octa­hedra share edges to built up zigzag chains extending parallel to [001]. The two types of chains are condensed by common vertices into a framework structure. The crystal structure can alternatively be described as derived from a distorted hexa­gonally closed packed arrangement of the O atoms, with Zn and Mo in half of the octa­hedral voids.We acknowledge financial support from the Spanish Ministerio de Economía y Competitividad (MAT2013–40950-R), Gobierno del Principado de Asturias (GRUPIN14–060) and ERDF.Peer ReviewedInternational Union of CrystallographyEuropean CommissionPrincipado de AsturiasMinisterio de Economía y Competitividad (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2016201620152016info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/137469reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-40950-Rhttp://dx.doi.org/10.1107/S205698901501186XSíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1374692026-05-22T06:33:51Z
dc.title.none.fl_str_mv Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction data
title Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction data
spellingShingle Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction data
Mtioui-Sghaier, Olfa
Crystal structures
Redetermination
Wolframite structure type
Hydro­thermal synthesis
β-ZnMoO4
title_short Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction data
title_full Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction data
title_fullStr Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction data
title_full_unstemmed Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction data
title_sort Redetermination of the crystal structure of β-zinc molybdate from single-crystal X-ray diffraction data
dc.creator.none.fl_str_mv Mtioui-Sghaier, Olfa
Mendoza-Meroño, Rafael
Ktari, Lilia
Dammak, Mohamed
García-Granda, Santiago
author Mtioui-Sghaier, Olfa
author_facet Mtioui-Sghaier, Olfa
Mendoza-Meroño, Rafael
Ktari, Lilia
Dammak, Mohamed
García-Granda, Santiago
author_role author
author2 Mendoza-Meroño, Rafael
Ktari, Lilia
Dammak, Mohamed
García-Granda, Santiago
author2_role author
author
author
author
dc.contributor.none.fl_str_mv European Commission
Principado de Asturias
Ministerio de Economía y Competitividad (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Crystal structures
Redetermination
Wolframite structure type
Hydro­thermal synthesis
β-ZnMoO4
topic Crystal structures
Redetermination
Wolframite structure type
Hydro­thermal synthesis
β-ZnMoO4
description This is an open-access article distributed under the terms of the Creative Commons Attribution Licence.
publishDate 2015
dc.date.none.fl_str_mv 2015
2016
2016
2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/137469
url http://hdl.handle.net/10261/137469
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-40950-R
http://dx.doi.org/10.1107/S205698901501186X
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.81155

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