O-O bond formation mediated by a hexanuclear iron complex supported on a stannoxane core

The FeIIcomplex of a hexanuclear non-heme ligand performs an OO bond formation reaction using iodosobenzene as the oxygen source. On the basis of infrared, UV/Vis, kinetic and DFT studies a radical coupled OO bond formation mechanism is proposed (see scheme). These findings are extremely important f...

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Detalles Bibliográficos
Autores: Kundu, Subrata, Matito i Gras, Eduard, Walleck, Stephan, Pfaff, Florian F., Heims, Florian, Rábay, Battist, Luis Luis, Josep Maria, Company Casadevall, Anna, Braun-Cula, Beatrice, Glaser, Thorsten, Ray, Kallol
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2012
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/16590
Acceso en línea:http://hdl.handle.net/10256/16590
Access Level:acceso abierto
Palabra clave:Funcional de densitat, Teoria del
Density functionals
Oxidació
Oxidation
Catalitzadors
Catalysts
Descripción
Sumario:The FeIIcomplex of a hexanuclear non-heme ligand performs an OO bond formation reaction using iodosobenzene as the oxygen source. On the basis of infrared, UV/Vis, kinetic and DFT studies a radical coupled OO bond formation mechanism is proposed (see scheme). These findings are extremely important for the design and discovery of faster and cheaper water oxidation catalysts

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