Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts

The direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands i...

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Detalles Bibliográficos
Autores: Rivilla de la Cruz, Iván, Gómez Emeterio, Bella Pilar, Romero Fructos-Vázquez, Manuel, Díaz Requejo, María Mar, Pérez Romero, Pedro José
Tipo de recurso: artículo
Fecha de publicación:2011
País:España
Institución:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:inglés
OAI Identifier:oai:ariasmontano.uhu.es:10272/11556
Acceso en línea:http://hdl.handle.net/10272/11556
Access Level:acceso abierto
Palabra clave:Gold catalysis
Carbene transfer
C-H functionalization
NHC ligands
Diazo compounds
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spelling Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based CatalystsRivilla de la Cruz, IvánGómez Emeterio, Bella PilarRomero Fructos-Vázquez, ManuelDíaz Requejo, María MarPérez Romero, Pedro JoséGold catalysisCarbene transferC-H functionalizationNHC ligandsDiazo compoundsThe direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developedAmerican Chemical Society20112011-01-0120112011-01-01journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10272/11556reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelvainstname:Universidad de Huelva (UHU)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Atribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:ariasmontano.uhu.es:10272/115562026-06-02T14:58:11Z
dc.title.none.fl_str_mv Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
title Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
spellingShingle Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
Rivilla de la Cruz, Iván
Gold catalysis
Carbene transfer
C-H functionalization
NHC ligands
Diazo compounds
title_short Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
title_full Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
title_fullStr Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
title_full_unstemmed Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
title_sort Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
dc.creator.none.fl_str_mv Rivilla de la Cruz, Iván
Gómez Emeterio, Bella Pilar
Romero Fructos-Vázquez, Manuel
Díaz Requejo, María Mar
Pérez Romero, Pedro José
author Rivilla de la Cruz, Iván
author_facet Rivilla de la Cruz, Iván
Gómez Emeterio, Bella Pilar
Romero Fructos-Vázquez, Manuel
Díaz Requejo, María Mar
Pérez Romero, Pedro José
author_role author
author2 Gómez Emeterio, Bella Pilar
Romero Fructos-Vázquez, Manuel
Díaz Requejo, María Mar
Pérez Romero, Pedro José
author2_role author
author
author
author
dc.contributor.none.fl_str_mv
dc.subject.none.fl_str_mv Gold catalysis
Carbene transfer
C-H functionalization
NHC ligands
Diazo compounds
topic Gold catalysis
Carbene transfer
C-H functionalization
NHC ligands
Diazo compounds
description The direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developed
publishDate 2011
dc.date.none.fl_str_mv 2011
2011-01-01
2011
2011-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10272/11556
url http://hdl.handle.net/10272/11556
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelva
instname:Universidad de Huelva (UHU)
instname_str Universidad de Huelva (UHU)
reponame_str Arias Montano. Repositorio Institucional de la Universidad de Huelva
collection Arias Montano. Repositorio Institucional de la Universidad de Huelva
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,81155

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