Quantifying Ice-Sheet Derived Lead (Pb) Fluxes to the Ocean; A Case Study at Nioghalvfjerdsbræ

Concentrations of the toxic element lead (Pb) are elevated in seawater due to historical emissions. While anthropogenic atmospheric emissions are the dominant source of dissolved Pb (dPb) to the Atlantic Ocean, evidence is emerging of a natural source associated with subglacial discharge into the oc...

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Detalhes bibliográficos
Autores: Krisch, Stephan, Huhn, Oliver, Al-Hashem, Ali, Hopwood, Mark J., Lodeiro, Pablo, Achterberg, Eric P.
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Recursos:Universitat de Lleida (UdL)
Repositorio:Repositori Obert UdL
OAI Identifier:oai:repositori.udl.cat:10459.1/84452
Acesso em linha:https://doi.org/10.1029/2022GL100296
http://hdl.handle.net/10459.1/84452
Access Level:acceso abierto
Palavra-chave:Arctic
GEOTRACES
Greenland ice sheet
Lead fluxes
Marine-terminating glacier
Nioghalvfjerdsbrae
Glaceres
Plom
Descrição
Resumo:Concentrations of the toxic element lead (Pb) are elevated in seawater due to historical emissions. While anthropogenic atmospheric emissions are the dominant source of dissolved Pb (dPb) to the Atlantic Ocean, evidence is emerging of a natural source associated with subglacial discharge into the ocean but this has yet to be constrained around Greenland. Here, we show subglacial discharge from the cavity underneath Nioghalvfjerdsbræ floating ice tongue, is a previously unrecognized source of dPb to the NE Greenland Shelf. Contrasting cavity-inflowing and cavity-outflowing waters, we constrain the associated net-dPb flux as 2.2 ± 1.4 Mg·yr−1, of which ∼90% originates from dissolution of glacial bedrock and cavity sediments. We propose that the retreat of the floating ice tongue, the ongoing retreat of many glaciers on Greenland, associated shifts in sediment dynamics, and enhanced meltwater discharges into shelf waters may result in pronounced changes, possibly increases, in net-dPb fluxes to coastal waters.