Uso de radiación solar simulada y peróxido de hidrógeno en la eliminación de azitromicina de soluciones acuosas: optimización y análisis de mineralización

Azithromycin (AZT) is a broad-spectrum antibiotic from the group of macrolides that acts against several Gram-positive and Gram-negative bacteria, which has promoted its use in the treatment of different respiratory and sexually transmitted diseases. However, its presence in environmental matrices a...

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Detalhes bibliográficos
Autores: Cano Carvajal, Pablo Andrés, Jaramillo Baquero, Marcela, Zúñiga Benítez, Henry Nelson, Londoño Cañas, Yudy Andrea, Peñuela Mesa, Gustavo Antonio
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:Colombia
Recursos:Tecnológico de Antioquia
Repositorio:Repositorio Tdea
Idioma:inglés
OAI Identifier:oai:dspace.tdea.edu.co:tdea/2785
Acesso em linha:https://dspace.tdea.edu.co/handle/tdea/2785
Access Level:acceso abierto
Palavra-chave:Antibiotics
Antibióticos
Azitromicina
Hydrogen peroxide
Peróxido de hidrógeno
Peróxido de hidrogénio
Azithromycin
Sunlight
Luz Solar
Wastewater Treatment
Advanced oxidation
Descrição
Resumo:Azithromycin (AZT) is a broad-spectrum antibiotic from the group of macrolides that acts against several Gram-positive and Gram-negative bacteria, which has promoted its use in the treatment of different respiratory and sexually transmitted diseases. However, its presence in environmental matrices and in the effluents of conventional wastewater treatment plants has been evidenced in recent years, which reflects the need to develop new treatment alternatives that allow its total removal and minimize the eventual adverse effects, selection of resistant bacterial strains, associated with its presence in water bodies. Simulated sunlight radiation and H2O2 were used to remove AZT from water assessing the effects of operational parameters like the solution initial pH and the peroxide concentration. Results indicate that hydroxyl free radical is the main responsible for pollutant removal but acidic solution conditions and larger H2O2 doses negatively affect OH generation under the evaluated experimental conditions. Pollutant removal was almost complete after 120 min of photo-treatment. In addition, reduction of the organic carbon content in the treated samples was ~50.0%; and a significant increase of nitrates con- centration in solution was evidenced