Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
The equilibrium solubility and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K was reported. Mole fraction solubility varies continuously from 2.85 × 10–9 in neat water to 2.39 × 10–3 in neat 1,4-dioxane. Solubility behaviour was adequately correlated by...
| Autores: | , , , , , , |
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| Formato: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2023 |
| País: | Colombia |
| Recursos: | Universidad Cooperativa de Colombia |
| Repositorio: | Repositorio UCC |
| OAI Identifier: | oai:repository.ucc.edu.co:20.500.12494/50341 |
| Acesso em linha: | https://doi.org/10.1080/00319104.2017.1416613 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85041353886&doi=10.1080%2f00319104.2017.1416613&partnerID=40&md5=edc2ac8d735e4be979fd0c38c62138c0 https://hdl.handle.net/20.500.12494/50341 |
| Access Level: | acceso abierto |
| Palavra-chave: | EQUILIBRIUM SOLUBILITIES IKBI JOUYBAN-ACREE MODEL KIRKWOOD-BUFF INTEGRALS MIXTURES PREFERENTIAL SOLVATION SOLUBILITY SOLUTION THERMODYNAMICS SOLVATION SOLVENT COMPOSITION THERMODYNAMICS TRICLOCARBAN |
| Resumo: | The equilibrium solubility and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K was reported. Mole fraction solubility varies continuously from 2.85 × 10–9 in neat water to 2.39 × 10–3 in neat 1,4-dioxane. Solubility behaviour was adequately correlated by means of the Jouyban-Acree model. Based on the inverse Kirkwood-Buff integrals, preferential solvation parameters were calculated. Triclocarban is preferentially solvated by water in water-rich mixtures (0.00 < x1 < 0.18) and also in 1,4-dioxane-rich mixtures (0.78 < x1 < 1.00) but preferentially solvated by 1,4-dioxane in mixtures with similar solvent compositions. © 2017 Informa UK Limited, trading as Taylor & Francis Group |
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