Characterization of chitin and chitosan extracted from shrimp shells by two methods

ABSTRACT:Shrimp shells from Penaeus Vannamei species were hydrolyzed for chitin extraction by a chemical and a papain enzymatic method. Composition of shells was analyzed and their microstructure was characterized before and after hydrolysis by microscopy. Chitin fibers arrangement in the tissue was...

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Detalles Bibliográficos
Autores: Gartner Vargas, Carmiña, Peláez Jaramillo, Carlos Alberto, López Osorio, Betty Lucy
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2010
País:Colombia
Institución:Universidad de Antioquia
Repositorio:Repositorio UdeA
Idioma:inglés
OAI Identifier:oai:bibliotecadigital.udea.edu.co:10495/30854
Acceso en línea:https://hdl.handle.net/10495/30854
https://www.degruyter.com/document/doi/10.1515/epoly.2010.10.1.748/html
Access Level:acceso abierto
Palabra clave:Quitina
Chitin
Hidrólisis
Hydrolysis
Papaína
Papain
Shell microstructure
Descripción
Sumario:ABSTRACT:Shrimp shells from Penaeus Vannamei species were hydrolyzed for chitin extraction by a chemical and a papain enzymatic method. Composition of shells was analyzed and their microstructure was characterized before and after hydrolysis by microscopy. Chitin fibers arrangement in the tissue was preserved after chemical extraction, but after papain hydrolysis the tissue presented structural disarrangement indicating that papain reacts indistinctly with peptidic and N-acetyl linkages. Although chemical purification is very effective, by-products are not recoverable. Conversely, papain hydrolysis yields partially purified chitosan but permits aminoacids isolation, which is important in food industry. This method has other advantages such as low cost and easy accessibility of papain. Chitin and chitosan were characterized by thermogravimetric analysis, infrared spectrophotometry and capillary electrophoresis. Degree of N-acetylation (DA) was determined by cross-polarization magic angle spinning nuclear magnetic resonance (CPMAS 13CNMR) or potentiometry and crystallinity was measured by X ray diffraction.