Unsymmetrical cyrhetrenyl and ferrocenyl azines derived from 5-nitrofurane: synthesis, structural characterization and electrochemistry

A new series of unsymmetrical cyrhetrenyl and ferrocenyl azines that were monosubstituted [(eta(5)-C5H4)-C(R)=N-N=CH(5-NO2-2-C4H2O)]M {with M=Re(CO)(3) and R=H (1a) or R=Me (1b); M=Fe(eta(3)-C5H5) and R=H (2a) or R=Me (2b)} and disubstituted [Fe{(eta(5)-C

Detalhes bibliográficos
Autores: Gomez, Johana, Hugo Klahn, A, Fuentealba, Mauricio, Sierra, Diego, Olea-Azar, Claudio, Medina, Manuela E
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:Chile
Idioma:inglés
OAI Identifier:oai:repositorio.anid.cl:10533/232763
Acesso em linha:https://hdl.handle.net/10533/232763
Access Level:acceso abierto
Descrição
Resumo:A new series of unsymmetrical cyrhetrenyl and ferrocenyl azines that were monosubstituted [(eta(5)-C5H4)-C(R)=N-N=CH(5-NO2-2-C4H2O)]M {with M=Re(CO)(3) and R=H (1a) or R=Me (1b); M=Fe(eta(3)-C5H5) and R=H (2a) or R=Me (2b)} and disubstituted [Fe{(eta(5)-C