Metal containing cryptands as hosts for anions: evaluation of cu(i)center dot center dot center dot x and pi center dot center dot center dot x interactions in halide-tricopper(i) complexes through relativistic dft calculations

More selective than crown ethers, cryptands arise as suitable hosts for several ions, with the size of the cavity and the behavior of the atoms belonging to the structure being the main factors governing their selectivity. Similar to metallacrowns, inorg

Detalles Bibliográficos
Autores: Ponce-Vargas, Miguel, Muñoz-Castro, Álvaro Rafael
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2014
País:Chile
Idioma:inglés
OAI Identifier:oai:repositorio.anid.cl:10533/228767
Acceso en línea:https://hdl.handle.net/10533/228767
Access Level:acceso abierto
Descripción
Sumario:More selective than crown ethers, cryptands arise as suitable hosts for several ions, with the size of the cavity and the behavior of the atoms belonging to the structure being the main factors governing their selectivity. Similar to metallacrowns, inorg