ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS

Modified electrodes with transition metal phenantrolines, phthalocyanines, porphyrins and other complexes where the metal center is a transition metal have been widely studied because they show highly activity toward the oxidation and reduction of several analytes. One of the most interesting applic...

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Autores: Aguirre Quintana, Maria Jesus, Chen Carrillo, Yo-Ying Adriana, Cheuquepan, William, Isaacs Casanova, Mauricio Alejandro, Isaacs Socorro, Fabiola Maria, Ramirez Jofre, Galo
Tipo de documento: capítulo de livro
Estado:Versão publicada
Data de publicação:2009
País:Chile
Idioma:inglês
OAI Identifier:oai:repositorio.anid.cl:10533/165285
Acesso em linha:https://hdl.handle.net/10533/165285
Access Level:Acceso aberto
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spelling Ramirez Jofre, GaloIsaacs Socorro, Fabiola MariaIsaacs Casanova, Mauricio AlejandroCheuquepan, WilliamChen Carrillo, Yo-Ying AdrianaAguirre Quintana, Maria Jesus2009https://hdl.handle.net/10533/165285http://purl.org/coar/access_right/c_abf2ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS420341Aguirre Quintana, Maria JesusChen Carrillo, Yo-Ying AdrianaCheuquepan, WilliamIsaacs Casanova, Mauricio AlejandroIsaacs Socorro, Fabiola MariaRamirez Jofre, GaloEsposito, RichardConti, Antonio2016-12-27T21:49:35Z2022-06-17T20:35:23Z2016-12-27T21:49:35Z2022-06-17T20:35:23Z2009Modified electrodes with transition metal phenantrolines, phthalocyanines, porphyrins and other complexes where the metal center is a transition metal have been widely studied because they show highly activity toward the oxidation and reduction of several analytes. One of the most interesting applications of these modified electrodes is the determination of oxoanions in waste water, food and beverages. In fact, they have been used to detect nitrite, nitrate, sulfite, and other pollutants or traces with low limit detection and in some cases; specificity. On the other hand, it is interesting that these modified electrodes can be designed for desirable purposes by changing the metal center, modifying the ligand, or changing the electrolyte. There are some cases in which the position of a substituent on the ligand can drastically change its activity. The modified electrodes are been used as supramolecular assemblies, as electroactive films or as composites of different layers adsorbed on the surface. This brief review shows the last decade's studies on the detection of sulfur and nitrogen oxoanions using electrodes modified with metal transition complexes. © 2009 Nova Science Publishers, Inc. All rights reserved.FONDECYT459FONDECYT11075048978-1606927731 https://hdl.handle.net/10533/165285engNOVA SCIENCE PUBLISHERSinstname: Conicytreponame: Repositorio Digital RI2.0instname: Conicytreponame: Repositorio Digital RI 2.0info:eu-repo/grantAgreement/Fondecyt/11075048info:eu-repo/semantics/dataset/hdl.handle.net/10533/93479info:eu-repo/semantics/openAccessELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONSPOLYMER ELECTROLYTE MEMBRANE FUEL CELLS AND ELECTROCATALYSTSCapitulo de libroinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/bookPartCapituloLibrohttps://hdl.handle.net/10533/165285FONDECYThttp://purl.org/coar/resource_type/c_32488d5b8d29-4170-471b-9579-1cee4af8dfedvirtual::11221-18d5b8d29-4170-471b-9579-1cee4af8dfedvirtual::11221-110533/165285oai:repositorio.anid.cl:10533/1652852023-07-03 23:51:30.877https://repositorio.anid.clRepositorio ANIDaletelier@anid.cl
dc.title.none.fl_str_mv ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS
dc.title.libro.none.fl_str_mv POLYMER ELECTROLYTE MEMBRANE FUEL CELLS AND ELECTROCATALYSTS
title ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS
spellingShingle ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS
Aguirre Quintana, Maria Jesus
title_short ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS
title_full ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS
title_fullStr ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS
title_full_unstemmed ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS
title_sort ELECTROCATALYTIC MODIFIED ELECTRODES WITH TRANSITION METAL AZAMACROCYCLES AND OTHER COMPLEXES FOR THE DETECTION OF SULFUR AND NITROGEN OXOANIONS
dc.creator.none.fl_str_mv Aguirre Quintana, Maria Jesus
Chen Carrillo, Yo-Ying Adriana
Cheuquepan, William
Isaacs Casanova, Mauricio Alejandro
Isaacs Socorro, Fabiola Maria
Ramirez Jofre, Galo
dc.creator.libro.none.fl_str_mv Esposito, Richard
Conti, Antonio
author Aguirre Quintana, Maria Jesus
author_facet Aguirre Quintana, Maria Jesus
Chen Carrillo, Yo-Ying Adriana
Cheuquepan, William
Isaacs Casanova, Mauricio Alejandro
Isaacs Socorro, Fabiola Maria
Ramirez Jofre, Galo
author_role author
author2 Chen Carrillo, Yo-Ying Adriana
Cheuquepan, William
Isaacs Casanova, Mauricio Alejandro
Isaacs Socorro, Fabiola Maria
Ramirez Jofre, Galo
author2_role author
author
author
author
author
description Modified electrodes with transition metal phenantrolines, phthalocyanines, porphyrins and other complexes where the metal center is a transition metal have been widely studied because they show highly activity toward the oxidation and reduction of several analytes. One of the most interesting applications of these modified electrodes is the determination of oxoanions in waste water, food and beverages. In fact, they have been used to detect nitrite, nitrate, sulfite, and other pollutants or traces with low limit detection and in some cases; specificity. On the other hand, it is interesting that these modified electrodes can be designed for desirable purposes by changing the metal center, modifying the ligand, or changing the electrolyte. There are some cases in which the position of a substituent on the ligand can drastically change its activity. The modified electrodes are been used as supramolecular assemblies, as electroactive films or as composites of different layers adsorbed on the surface. This brief review shows the last decade's studies on the detection of sulfur and nitrogen oxoanions using electrodes modified with metal transition complexes. © 2009 Nova Science Publishers, Inc. All rights reserved.
publishDate 2009
dc.date.issued.none.fl_str_mv 2009
dc.date.accessioned.none.fl_str_mv 2016-12-27T21:49:35Z
2022-06-17T20:35:23Z
dc.date.available.none.fl_str_mv 2016-12-27T21:49:35Z
2022-06-17T20:35:23Z
dc.type.none.fl_str_mv Capitulo de libro
info:eu-repo/semantics/publishedVersion
dc.type.driver.none.fl_str_mv info:eu-repo/semantics/bookPart
format bookPart
status_str publishedVersion
dc.identifier.folio.none.fl_str_mv 11075048
dc.identifier.isbn.none.fl_str_mv 978-1606927731 
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/10533/165285
identifier_str_mv 11075048
978-1606927731 
url https://hdl.handle.net/10533/165285
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv instname: Conicyt
reponame: Repositorio Digital RI2.0
instname: Conicyt
reponame: Repositorio Digital RI 2.0
dc.relation.projectid.none.fl_str_mv info:eu-repo/grantAgreement/Fondecyt/11075048
dc.relation.set.none.fl_str_mv info:eu-repo/semantics/dataset/hdl.handle.net/10533/93479
dc.rights.driver.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.editorial.none.fl_str_mv NOVA SCIENCE PUBLISHERS
repository.name.fl_str_mv Repositorio ANID
repository.mail.fl_str_mv aletelier@anid.cl
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score 15,811543

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