From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant properties
Bananas are among the most produced fruits globally, and their industry generates substantial amounts of peels, which are currently underutilized. Therefore, a simple process was proposed to fully convert banana peel powder (BPP) into bioplastic films using mild pretreatments. The influence of the f...
| Autores: | , , , , , , , |
|---|---|
| Formato: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2024 |
| País: | Brasil |
| Recursos: | Universidade Estadual Paulista (UNESP) |
| Repositorio: | Repositório Institucional da UNESP |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.unesp.br:11449/297493 |
| Acesso em linha: | http://dx.doi.org/10.1016/j.jclepro.2024.140709 https://hdl.handle.net/11449/297493 |
| Access Level: | acceso abierto |
| Palavra-chave: | Antioxidant activity Banana peel Bioplastic film Hydrothermal pretreatment UV-Blocking |
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From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant propertiesAntioxidant activityBanana peelBioplastic filmHydrothermal pretreatmentUV-BlockingBananas are among the most produced fruits globally, and their industry generates substantial amounts of peels, which are currently underutilized. Therefore, a simple process was proposed to fully convert banana peel powder (BPP) into bioplastic films using mild pretreatments. The influence of the following variables on film performance was investigated: the type of BPP (unblanched versus blanched), the pretreatment solvent (water – i.e., hydrothermal pretreatment, HTP – or sulfuric acid solution – i.e., dilute acid pretreatment, DAP), and the addition or not of carboxymethyl cellulose (CMC) in the films. The tensile properties of the bioplastics were primarily affected by the presence of CMC, with the films containing 20 wt% of this biopolymer achieving a tensile strength up to 16 MPa. The water vapor permeability was not influenced by any of the studied variables. In contrast, the water contact angle was primarily affected by the pretreatment employed, with all films prepared by HTP displaying a hydrophobic surface. The UV-shielding properties of the materials were mainly influenced by the type of BPP, and all films blocked at least 98% of UV radiation. The antioxidant activity was influenced primarily by the type of BPP, as blanching banana peels helped preserve it. These films are, therefore, promising materials for active food packaging applications, which could contribute to a transition toward a circular bioeconomy.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Nanotechnology National Laboratory for Agribusiness (LNNA) Embrapa Instrumentation, R. XV de Novembro, 1452 - Centro, SPBiochemical Processes Laboratory Embrapa Agroenergy, DFGraduate Program of Microbial Biology Institute of Biology University of Brasília, DFMaterials Engineering Department São Carlos School of Engineering (EESC) University of São Paulo (USP), SPChemistry Department Federal University of São Carlos (UFSCar), SPInstitute for Research in Bioenergy (IPBEN) São Paulo State University (UNESP), SPGraduate Program in Materials Science and Engineering (PPGCEM) & Department of Materials Engineering (DEMa) Federal University of São Carlos (UFSCar), SPInstitute for Research in Bioenergy (IPBEN) São Paulo State University (UNESP), SPFAPESP: 2017/22401–8FAPESP: 2020/11104–5FAPESP: 2021/05092–7CNPq: 423730/2021–5Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA)University of BrasíliaUniversidade de São Paulo (USP)Universidade Federal de São Carlos (UFSCar)Universidade Estadual Paulista (UNESP)2025-04-29T18:06:47Z2024-01-20info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1016/j.jclepro.2024.140709Journal of Cleaner Production, v. 438.0959-6526https://hdl.handle.net/11449/29749310.1016/j.jclepro.2024.1407092-s2.0-85184150063Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Cleaner Productioninfo:eu-repo/semantics/openAccessSilva, Rodrigo D.Pacheco, Thályta F.de Santi, Amanda D.Manarelli, FabianaBozzo, Breno R.Brienzo, Michel [UNESP]Otoni, Caio G.Azeredo, Henriette M.C.2025-04-30T14:30:32Zoai:repositorio.unesp.br:11449/297493Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestrepositoriounesp@unesp.bropendoar:29462025-04-30T14:30:32Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
| dc.title.none.fl_str_mv |
From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant properties |
| title |
From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant properties |
| spellingShingle |
From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant properties Silva, Rodrigo D. Antioxidant activity Banana peel Bioplastic film Hydrothermal pretreatment UV-Blocking |
| title_short |
From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant properties |
| title_full |
From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant properties |
| title_fullStr |
From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant properties |
| title_full_unstemmed |
From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant properties |
| title_sort |
From bulk banana peels to active materials: Slipping into bioplastic films with high UV-blocking and antioxidant properties |
| dc.creator.none.fl_str_mv |
Silva, Rodrigo D. Pacheco, Thályta F. de Santi, Amanda D. Manarelli, Fabiana Bozzo, Breno R. Brienzo, Michel [UNESP] Otoni, Caio G. Azeredo, Henriette M.C. |
| author |
Silva, Rodrigo D. |
| author_facet |
Silva, Rodrigo D. Pacheco, Thályta F. de Santi, Amanda D. Manarelli, Fabiana Bozzo, Breno R. Brienzo, Michel [UNESP] Otoni, Caio G. Azeredo, Henriette M.C. |
| author_role |
author |
| author2 |
Pacheco, Thályta F. de Santi, Amanda D. Manarelli, Fabiana Bozzo, Breno R. Brienzo, Michel [UNESP] Otoni, Caio G. Azeredo, Henriette M.C. |
| author2_role |
author author author author author author author |
| dc.contributor.none.fl_str_mv |
Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA) University of Brasília Universidade de São Paulo (USP) Universidade Federal de São Carlos (UFSCar) Universidade Estadual Paulista (UNESP) |
| dc.subject.por.fl_str_mv |
Antioxidant activity Banana peel Bioplastic film Hydrothermal pretreatment UV-Blocking |
| topic |
Antioxidant activity Banana peel Bioplastic film Hydrothermal pretreatment UV-Blocking |
| description |
Bananas are among the most produced fruits globally, and their industry generates substantial amounts of peels, which are currently underutilized. Therefore, a simple process was proposed to fully convert banana peel powder (BPP) into bioplastic films using mild pretreatments. The influence of the following variables on film performance was investigated: the type of BPP (unblanched versus blanched), the pretreatment solvent (water – i.e., hydrothermal pretreatment, HTP – or sulfuric acid solution – i.e., dilute acid pretreatment, DAP), and the addition or not of carboxymethyl cellulose (CMC) in the films. The tensile properties of the bioplastics were primarily affected by the presence of CMC, with the films containing 20 wt% of this biopolymer achieving a tensile strength up to 16 MPa. The water vapor permeability was not influenced by any of the studied variables. In contrast, the water contact angle was primarily affected by the pretreatment employed, with all films prepared by HTP displaying a hydrophobic surface. The UV-shielding properties of the materials were mainly influenced by the type of BPP, and all films blocked at least 98% of UV radiation. The antioxidant activity was influenced primarily by the type of BPP, as blanching banana peels helped preserve it. These films are, therefore, promising materials for active food packaging applications, which could contribute to a transition toward a circular bioeconomy. |
| publishDate |
2024 |
| dc.date.none.fl_str_mv |
2024-01-20 2025-04-29T18:06:47Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1016/j.jclepro.2024.140709 Journal of Cleaner Production, v. 438. 0959-6526 https://hdl.handle.net/11449/297493 10.1016/j.jclepro.2024.140709 2-s2.0-85184150063 |
| url |
http://dx.doi.org/10.1016/j.jclepro.2024.140709 https://hdl.handle.net/11449/297493 |
| identifier_str_mv |
Journal of Cleaner Production, v. 438. 0959-6526 10.1016/j.jclepro.2024.140709 2-s2.0-85184150063 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
Journal of Cleaner Production |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
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Universidade Estadual Paulista (UNESP) |
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UNESP |
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UNESP |
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Repositório Institucional da UNESP |
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Repositório Institucional da UNESP |
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Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
| repository.mail.fl_str_mv |
repositoriounesp@unesp.br |
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1853671843957833728 |
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15.301603 |