Direct synthesis of singular silver dendrites over TiO2 nanotubes using pentetic acid as capping agent

Silver dendritical nanostructures are known for their interesting electronic and optical properties com-pared to other Ag morphologies, vastly utilized for covering TiO2nanotubes. However, multiple stepsare required to assemble both of these structures. This paper reports a novel synthesis of vertic...

ver descrição completa

Detalhes bibliográficos
Autores: Bonatto, Fernando, Jardim, Maria Luisa Puga, Alves, Annelise Kopp, Silva, Jacqueline Arguello da, Lavayen, Vladimir, Bergmann, Carlos Perez
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2020
País:Brasil
Recursos:Universidade Federal do Rio Grande do Sul (UFRGS)
Repositório:Repositório Institucional da UFRGS
Idioma:inglês
OAI Identifier:oai:www.lume.ufrgs.br:10183/220775
Acesso em linha:http://hdl.handle.net/10183/220775
Access Level:Acceso aberto
Palavra-chave:Nanotubos
Anodização
Dióxido de titânio
DTPA
Dendritic growth
Anodization
Nanostructured materials
Interfaces
Descrição
Resumo:Silver dendritical nanostructures are known for their interesting electronic and optical properties com-pared to other Ag morphologies, vastly utilized for covering TiO2nanotubes. However, multiple stepsare required to assemble both of these structures. This paper reports a novel synthesis of verticallyaligned TiO2nanotubes covered by a forest of silver dendrites, obtained through the incorporation of elec-trodeposition (ED) cycle before the anodization process. Utilizing pentetic acid as a capping agent pro-motes superficial silver nucleation in both ED and anodization cycles. Also, testing varied ED cyclelengths provided information regarding the morphological evolution of the hierarchical silver structures,as some branches adopted a 90°angle from the central axis.