Application of a Zero-Valent Iron/Cork as Permeable Reactive Barrier for In Situ Remediation of Phenanthrene in Soil

This paper proposes an eco-efficient treatment technology for removing phenanthrene (PHE) from kaolinite soil, incorporating a permeable reactive barrier (PRB) in an electrokinetic (EK) remediation system, which was made by modifying the granulated cork (GC) with Fe@Fe2O3, identified as EK/Fe@Fe2O3/...

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Detalles Bibliográficos
Autores: Galvão, Álvaro G. P., Costa, Letícia G. A., Costa, Emily C. T. de A., da Silva, Djalma R., Martínez-Huitle, Carlos A. [UNESP], Vieira dos Santos, Elisama [UNESP]
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:Brasil
Institución:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/246553
Acceso en línea:http://dx.doi.org/10.3390/catal12121591
http://hdl.handle.net/11449/246553
Access Level:acceso abierto
Palabra clave:cork
electrokinetic remediation
permeable reactive barrier
phenanthrene
zero-valent iron
Descripción
Sumario:This paper proposes an eco-efficient treatment technology for removing phenanthrene (PHE) from kaolinite soil, incorporating a permeable reactive barrier (PRB) in an electrokinetic (EK) remediation system, which was made by modifying the granulated cork (GC) with Fe@Fe2O3, identified as EK/Fe@Fe2O3/GC. The novel product Fe@Fe2O3/GC was characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, and element mapping. EK tests were conducted to investigate the performance of the EK/Fe@Fe2O3/GC for removal of PHE from soil. The results showed that PHE was driven by the electro-osmotic flow toward the cathode and reacted with the EK/Fe@Fe2O3/GC. Further, the removal efficiency of PHE in the soil was higher in the presence of H2O2 due to the additional reactions achieved. The results were discussed in light of the existing literature.