Spatial and temporal distribution of perfluoroalkyl substances (PFAS) detected after an aqueous film forming foam (AFFF) spill
In 2015, > 460,000 L of aqueous film-forming foam (AFFF) and fire suppressors containing per- and polyfluoroalkyl substances (PFAS) were used to combat a fire at a petrochemical fuel storage terminal in the Port of Santos (Brazil). Sediments from seven sites were sampled repeatedly from 2 weeks t...
| Autores: | , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2024 |
| País: | Brasil |
| Institución: | Universidade Estadual Paulista (UNESP) |
| Repositorio: | Repositório Institucional da UNESP |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.unesp.br:11449/309139 |
| Acceso en línea: | http://dx.doi.org/10.1016/j.marpolbul.2024.116561 https://hdl.handle.net/11449/309139 |
| Access Level: | acceso abierto |
| Palabra clave: | Aqueous film forming foam (AFFF) PFAS PFHxA Santos Estuarine System Subtropical estuary |
| Sumario: | In 2015, > 460,000 L of aqueous film-forming foam (AFFF) and fire suppressors containing per- and polyfluoroalkyl substances (PFAS) were used to combat a fire at a petrochemical fuel storage terminal in the Port of Santos (Brazil). Sediments from seven sites were sampled repeatedly from 2 weeks to 1 year after the fire (n = 30). Ʃ15PFAS concentrations ranged from 115 to 15,931 pg g−1 dry weight (dw). Perfluorooctane sulfonic acid (PFOS) was the most frequently detected compound with concentrations ranging from 363 to 4517 (average = 1603) pg g−1dw to <47.1 to 642 (average = 401) pg g−1 dw, followed by perfluorohexanoic acid (PFHxA) (from 38.8 to 219 (average = 162) pg g−1 dw after 15 days and from <20.8 to 161 (average = 101) pg g−1 dw one year later). Together, the hydrodynamics and fire events documented in the region were important features explaining the spread of PFAS. |
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