Unveiling the Superiority of naphthylene over biphenylene in silicon carbide 2D Architectures

In recent years, silicon carbide (SiC) has once again become a target of interest in the materials science community, this time with particular interest in two-dimensional materials, which have attracted attention due to their large surface area and infinitesimal volume. In this sense, this study in...

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Detalles Bibliográficos
Autores: Laranjeira, Jose A.S. [UNESP], Martins, Nicolas F. [UNESP], Azevedo, Sérgio A., Denis, Pablo A., Sambrano, Julio R. [UNESP]
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:Brasil
Institución:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/299945
Acceso en línea:http://dx.doi.org/10.1016/j.commatsci.2025.113743
https://hdl.handle.net/11449/299945
Access Level:acceso abierto
Palabra clave:2D
Biphenylene
Naphthylene
SiC
Silicon carbide
2d
Carbide structure
Large surface area
Material science
Science community
Structure-based
Targets of interest
Two-dimensional materials
Descripción
Sumario:In recent years, silicon carbide (SiC) has once again become a target of interest in the materials science community, this time with particular interest in two-dimensional materials, which have attracted attention due to their large surface area and infinitesimal volume. In this sense, this study introduces a novel SiC structure based on the recently reported naphthylene lattice, termed INP-SiC. It compares its electronic, mechanical and vibrational properties with the well-reported biphenylene-like SiC (BPN-SiC) via density functional theory (DFT) simulations. Both monolayers are stable at 300 K and exhibit high electron mobility, with INP-SiC reaching 94.890 102 cm2/V.s. INP-SiC also shows superior mechanical robustness, with Young's modulus (171.65 N/m) comparable to g-SiC (178.02 N/m) and T-SiC (182.22 N/m). Overall, this work is dedicated to showing the INP-SiC potential as a multifunctional 2D platform.