Counter-Current Chromatography Separation of Isatin Derivatives using the Sandmeyer Methodology

A rapid and efficient method, using high-speed counter-current chromatography (HSCCC) technique, was developed for the separation of isomeric isatin derivatives, prepared following the Sandmeyer route. The biphasic solvent system composed of hexane:ethyl acetate:ethanol:water 1:0.5:0.5:1 (v/v/v/v) w...

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Detalles Bibliográficos
Autores: Almeida, Márcia R., Leitão, Gilda G., Silva, Bárbara V., Barbosa, Jussara P., Pinto, Angelo C.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2010
País:Brasil
Institución:Fundação Oswaldo Cruz (FIOCRUZ)
Repositorio:Repositório Institucional da FIOCRUZ (ARCA)
Idioma:inglés
OAI Identifier:oai:arca.fiocruz.br:icict/25720
Acceso en línea:https://arca.fiocruz.br/handle/icict/25720
Access Level:acceso abierto
Palabra clave:isatinas
Metodologia Sandmeyer
separação de isômeros
cromatografia de contra-corrente
isatins
Sandmeyer methodology
isomers separation
counter-current chromatography
Descripción
Sumario:A rapid and efficient method, using high-speed counter-current chromatography (HSCCC) technique, was developed for the separation of isomeric isatin derivatives, prepared following the Sandmeyer route. The biphasic solvent system composed of hexane:ethyl acetate:ethanol:water 1:0.5:0.5:1 (v/v/v/v) was used for all separations.