Avaliação do híbrido CTA-MCM-41, modificado por poliestireno, na transesterificação catalítica de monoéster
The present work shows a new technique applied to the synthesis of heterogeneous catalysts MCM-41 containing basic alkylammonium cations and the study of stability in the transesterification reactions of monoesters. MCM-41 was developed by Mobil Oil Corporation in 1992 due to demand for materials wi...
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| Tipo de recurso: | tesis doctoral |
| Estado: | Versión publicada |
| Fecha de publicación: | 2013 |
| País: | Brasil |
| Institución: | Universidade Federal de São Carlos (UFSCAR) |
| Repositorio: | Repositório Institucional da UFSCAR |
| Idioma: | portugués |
| OAI Identifier: | oai:repositorio.ufscar.br:20.500.14289/3925 |
| Acceso en línea: | https://repositorio.ufscar.br/handle/20.500.14289/3925 |
| Access Level: | acceso abierto |
| Palabra clave: | Transesterificação Catálise heterogênea MCM-41 Biodiesel ENGENHARIAS::ENGENHARIA QUIMICA |
| Sumario: | The present work shows a new technique applied to the synthesis of heterogeneous catalysts MCM-41 containing basic alkylammonium cations and the study of stability in the transesterification reactions of monoesters. MCM-41 was developed by Mobil Oil Corporation in 1992 due to demand for materials with pore diameters in the range of mesoporous and is characterized by the arrangement of hexagonally ordered channels. Its synthesis involves precursors such as silicon source, hydroxyl source and surfactant, this latter in aqueous solution assumes the provision more favorable to their bi-functional character, forming a structure called a micelle. Recent polls show MCM-41, containing alkylammonium cations as an excellent base catalyst in fine chemistry and applicability in the production of biodiesel possessing strong basic sites related to the presence of anions siloxy ≡SiO- from interacting with the surfactant alkylammonium cations. The potential for reuse of heterogeneous catalysts brings economic benefits to the chemical processes involved, but the stability is needed in the different uses and leaching of these cations to the reaction observed in the different uses of the catalysts MCM-41 CTA+ reconciled to the loss of catalytic activity observed in literature motivated the search for new methods of synthesis with the aim of setting alkylammonium cations (CTA+) in the catalyst micelles. With this objective the styrene was used in synthesizing and expanding agent micellar enabling it inside the micelles and subsequent polymerization. X-ray diffraction, infrared spectroscopy in the region, elementary chemical analysis (CHN) techniques were used for characterization of new materials poly (styrene)-MCM-41 CTA+. The new catalysts provide high conversions (82%) transesterification of monoester (ethyl acetate) and methanol (1:6) at 50 ° C and were more stable catalytic achieving the proposed objective. |
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