Performance evaluation of titanium oxide deposited by electrophoresis in photoelectrodes of dye-sensitized solar cells

ABSTRACT Nanoparticles of TiO2 have been the main semiconductor applied in Dye-sensitized solar cells (DSSCs). In this work, solar cells were developed from the electrophoretic deposition of anatase titanium dioxide (TiO2) films on conductive glasses. The electrophoretic deposition was perfomed with...

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Detalles Bibliográficos
Autores: Souza,Antonio Paulo Santos, Cavalcante,Natália Macêdo, Freire,Francisco Nivaldo Aguiar, Almeida,Ana Fabíola Leite
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:Brasil
Institución:Matéria (Rio de Janeiro. Online)
Repositorio:Matéria (Rio de Janeiro. Online)
Idioma:inglés
OAI Identifier:oai:scielo:S1517-70762021000100338
Acceso en línea:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762021000100338
Access Level:acceso abierto
Palabra clave:Dye-sensitized solar cells
Electrophoresis
Titanium dioxide
Film
Mesoporous. Photoanode
Descripción
Sumario:ABSTRACT Nanoparticles of TiO2 have been the main semiconductor applied in Dye-sensitized solar cells (DSSCs). In this work, solar cells were developed from the electrophoretic deposition of anatase titanium dioxide (TiO2) films on conductive glasses. The electrophoretic deposition was perfomed with a constant voltage of 80V for 2 minutes and, after drying, the films were sintered at three different temperatures: 450 °C, 550 °C and 600 °C. In the assembly of the cells, the titanium dioxide films were sensitized by Ruthenizer 535-bisTBA dye (N719) and an electrolyte containing the iodide / tri-iodide redox pair and a commercial transparent platinum counter electrode were used. TiO2 films were characterized by scanning electron microscopy, dispersive energy spectroscopy and X-ray diffraction and photo-electrochemical techniques. The energy conversion rates were 0.2646% for the sintered film at 450 °C, 0.1209% for the sintered film at 550 °C and 0.1137% for the film sintered at 600 °C.