Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bonds

In this current work, a brief historical narrative of the most popular theories that decisively aid in the comprehension of the hydrogen bond formation is presented. As is well-known, the valence bond theory was efficiently suitable to certify the electronic structure of Lewis acids/bases, in partic...

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Autor: de Oliveira, Boaz Galdino
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:Brasil
Recursos:Universidade Federal de Mato Grosso do Sul (UFMS)
Repositorio:Orbital - The Electronic Journal of Chemistry (Campo Grande)
Idioma:inglés
OAI Identifier:oai:periodicos.ufms.br:article/15941
Acesso em linha:https://periodicos.ufms.br/index.php/orbital/article/view/15941
Access Level:acceso abierto
Palavra-chave:acetylene
ethylene
cyclopropane
hydrogen bond
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spelling Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bondsacetyleneethylenecyclopropanehydrogen bondIn this current work, a brief historical narrative of the most popular theories that decisively aid in the comprehension of the hydrogen bond formation is presented. As is well-known, the valence bond theory was efficiently suitable to certify the electronic structure of Lewis acids/bases, in particular the fluorine, oxygen and nitrogen as high charge density sources, and as such the homodimers of 2(HF), 2(H2O) and 2(NH3) were framed as reference systems. Regarding the π bonds of acetylene and ethylene as well as the p-π (pseudo unsaturated bond) clouds of cyclopropane, these compounds belong to a distinct group of proton receptors by which the π···H, p-π···H and C···H hydrogen bonds are formed. DOI: http://dx.doi.org/10.17807/orbital.v11i3.1399Instituto de Química, Universidade Federal de Mato Grosso do Sul2019-07-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufms.br/index.php/orbital/article/view/15941Orbital: The Electronic Journal of Chemistry; Orbital - Vol. 11 No. 3 - April-June 2019; 205-218Orbital: The Electronic Journal of Chemistry; Orbital - Vol. 11 No. 3 - April-June 2019; 205-2181984-6428reponame:Orbital - The Electronic Journal of Chemistry (Campo Grande)instname:Universidade Federal de Mato Grosso do Sul (UFMS)instacron:UFMSenghttps://periodicos.ufms.br/index.php/orbital/article/view/15941/10904Copyright (c) 2019 Orbital: The Electronic Journal of Chemistryhttps://creativecommons.org/licenses/by-nc-nd/4.0info:eu-repo/semantics/openAccessde Oliveira, Boaz Galdino2023-01-20T10:52:23Zoai:periodicos.ufms.br:article/15941Revistahttps://periodicos.ufms.br/index.php/orbital/indexPUBhttps://periodicos.ufms.br/index.php/orbital/oaieditor.orbital@ufms.br || marcos.amaral@ufms.br1984-64281984-6428opendoar:2023-01-20T10:52:23Orbital - The Electronic Journal of Chemistry (Campo Grande) - Universidade Federal de Mato Grosso do Sul (UFMS)false
dc.title.none.fl_str_mv Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bonds
title Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bonds
spellingShingle Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bonds
de Oliveira, Boaz Galdino
acetylene
ethylene
cyclopropane
hydrogen bond
title_short Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bonds
title_full Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bonds
title_fullStr Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bonds
title_full_unstemmed Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bonds
title_sort Hydrocarbons as Proton Receptors and Evidences of Unconventional and Unusual π···H, p-π···H and C···H Hydrogen Bonds
dc.creator.none.fl_str_mv de Oliveira, Boaz Galdino
author de Oliveira, Boaz Galdino
author_facet de Oliveira, Boaz Galdino
author_role author
dc.subject.por.fl_str_mv acetylene
ethylene
cyclopropane
hydrogen bond
topic acetylene
ethylene
cyclopropane
hydrogen bond
description In this current work, a brief historical narrative of the most popular theories that decisively aid in the comprehension of the hydrogen bond formation is presented. As is well-known, the valence bond theory was efficiently suitable to certify the electronic structure of Lewis acids/bases, in particular the fluorine, oxygen and nitrogen as high charge density sources, and as such the homodimers of 2(HF), 2(H2O) and 2(NH3) were framed as reference systems. Regarding the π bonds of acetylene and ethylene as well as the p-π (pseudo unsaturated bond) clouds of cyclopropane, these compounds belong to a distinct group of proton receptors by which the π···H, p-π···H and C···H hydrogen bonds are formed. DOI: http://dx.doi.org/10.17807/orbital.v11i3.1399
publishDate 2019
dc.date.none.fl_str_mv 2019-07-06
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://periodicos.ufms.br/index.php/orbital/article/view/15941
url https://periodicos.ufms.br/index.php/orbital/article/view/15941
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv https://periodicos.ufms.br/index.php/orbital/article/view/15941/10904
dc.rights.driver.fl_str_mv Copyright (c) 2019 Orbital: The Electronic Journal of Chemistry
https://creativecommons.org/licenses/by-nc-nd/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Copyright (c) 2019 Orbital: The Electronic Journal of Chemistry
https://creativecommons.org/licenses/by-nc-nd/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Instituto de Química, Universidade Federal de Mato Grosso do Sul
publisher.none.fl_str_mv Instituto de Química, Universidade Federal de Mato Grosso do Sul
dc.source.none.fl_str_mv Orbital: The Electronic Journal of Chemistry; Orbital - Vol. 11 No. 3 - April-June 2019; 205-218
Orbital: The Electronic Journal of Chemistry; Orbital - Vol. 11 No. 3 - April-June 2019; 205-218
1984-6428
reponame:Orbital - The Electronic Journal of Chemistry (Campo Grande)
instname:Universidade Federal de Mato Grosso do Sul (UFMS)
instacron:UFMS
instname_str Universidade Federal de Mato Grosso do Sul (UFMS)
instacron_str UFMS
institution UFMS
reponame_str Orbital - The Electronic Journal of Chemistry (Campo Grande)
collection Orbital - The Electronic Journal of Chemistry (Campo Grande)
repository.name.fl_str_mv Orbital - The Electronic Journal of Chemistry (Campo Grande) - Universidade Federal de Mato Grosso do Sul (UFMS)
repository.mail.fl_str_mv editor.orbital@ufms.br || marcos.amaral@ufms.br
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score 15,301603

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