Optimizing strength and corrosion resistance of the metastable β-alloy Ti–35Nb–7Zr–5Ta alloy by equal-channel angular pressing

Controlling the microstructure of the Ti–35Nb–7Zr–5Ta alloy is fundamental for enhancing its strength and corrosion resistance in biomedical applications. This study examines how microstructural evolution through equal-channel angular pressing (ECAP) at room temperature and 300 °C influences Young&#...

Descripción completa

Detalles Bibliográficos
Autores: Silva, R., Silva, J., Viana, C. C., Afonso, C. R.M., Hammer, P. [UNESP], Magalhães, D. C.C., Plaine, A. H., Rovere, C. A.D.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:Brasil
Institución:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/303676
Acceso en línea:http://dx.doi.org/10.1016/j.jmrt.2025.01.136
https://hdl.handle.net/11449/303676
Access Level:acceso abierto
Palabra clave:ECAP
EIS
Microstructure
Polarization
XPS analysis
Young's modulus
β-titanium alloy
Descripción
Sumario:Controlling the microstructure of the Ti–35Nb–7Zr–5Ta alloy is fundamental for enhancing its strength and corrosion resistance in biomedical applications. This study examines how microstructural evolution through equal-channel angular pressing (ECAP) at room temperature and 300 °C influences Young's modulus, hardness, and corrosion resistance. ECAP refines grain size and promotes nanocrystalline β-phase grains, α phase decomposition, and ω phase precipitation. Room temperature ECAP decreases Young's modulus by reducing the β-phase stability due to deformation, while 300 °C processing enhances hardness and Young's modulus due to finer microstructure and higher ω-phase fraction. Grain refinement accelerates passivation kinetics, enhancing corrosion resistance with a thicker and less defective passive film, especially at 300 °C, without significant changes in the elemental composition of the outer passive film.