Spin-phonon coupling in uniaxial anisotropic spin-glass based on Fe2TiO5 pseudobrookite
The ferric pseudobrookite is a rare example of uniaxial anisotropic spin-glass insulator, depicting a multiglass behavior and magnetoelectric coupling. Here, we present Raman spectroscopy results in order to elucidate the spin-phonon coupling in Fe2TiO5 for the first time. The experimental data are...
| Autores: | , , , , , , , , , , |
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| Formato: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2019 |
| País: | Brasil |
| Recursos: | Universidade Estadual Paulista (UNESP) |
| Repositorio: | Repositório Institucional da UNESP |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.unesp.br:11449/187724 |
| Acesso em linha: | http://dx.doi.org/10.1016/j.jallcom.2019.05.343 http://hdl.handle.net/11449/187724 |
| Access Level: | acceso abierto |
| Palavra-chave: | Anisotropic spin-glass DFT phonon Fe2TiO5 Magnetoelectric Spin-phonon coupling Theoretical Raman |
| Resumo: | The ferric pseudobrookite is a rare example of uniaxial anisotropic spin-glass insulator, depicting a multiglass behavior and magnetoelectric coupling. Here, we present Raman spectroscopy results in order to elucidate the spin-phonon coupling in Fe2TiO5 for the first time. The experimental data are supported by computational simulations performed in view of density functional theory, which allowed us to assign the main Raman-active modes. Temperature-dependent phonon behavior exhibited anomalous evolution around 55 and 80–200 K, which was explained as successive coupling between lattice and spin configuration arising from spin freezing and short-range magnetic correlation, respectively. Arguments that the magnetoelectric effect in Fe2TiO5 is mediated by spin-phonon coupling are presented. |
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