Application of an Agro-Waste for the Immobilization of Microbial Fructosyltransferase: A New Alternative for Fructooligosaccharide Production

This work evaluated the use of corncob as a support for the immobilization of an extracellular fructosyltransferase (E.C. 2.4.1.9) from Aspergillus oryzae IPT-301, aiming at the synthesis of a stable biocatalyst for the production of fructooligosaccharides. The transfructosylation activity of the im...

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Detalles Bibliográficos
Autores: Pereira, Richard S., Vieira, Ana C., Leite, Paula C., Maestrelli, Sylma C., Silva, Elda S., Maiorano, Alfredo E., Xavier, Michelle C.A., Lopes, Melina S., de Paula, Ariela V. [UNESP], Morales, Sergio A.V., Perna, Rafael F.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:Brasil
Institución:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/302064
Acceso en línea:http://dx.doi.org/10.21577/0103-5053.20240172
https://hdl.handle.net/11449/302064
Access Level:acceso abierto
Palabra clave:corncob
fructooligosaccharides
fructosyltransferase
immobilized enzyme
Descripción
Sumario:This work evaluated the use of corncob as a support for the immobilization of an extracellular fructosyltransferase (E.C. 2.4.1.9) from Aspergillus oryzae IPT-301, aiming at the synthesis of a stable biocatalyst for the production of fructooligosaccharides. The transfructosylation activity of the immobilized enzyme was maximized via experimental design. Additionally, the biochemical properties and stability of the immobilized enzyme, as well as the reaction kinetics, were determined. The enzyme immobilized on alkali-treated corncob showed the highest transfructosylation activity at 50 °C and pH 5.5. It also presented a wide pH stability and a half-life around 1.4 times greater than the soluble enzyme. Furthermore, the immobilized enzyme showed 53% of retention of catalytic activity in a second consecutive reaction cycle, showing the potential for reuse. These results suggest that alkali-treated corncob is a promising support material for the synthesis of heterogeneous biocatalysts aiming at fructooligosaccharide production, which can contribute to the valorization of this abundant agro-waste.